The debatable role of singlet oxygen in persulfate-based advanced oxidation processes

L Wang, K Xiao, H Zhao - Water Research, 2023 - Elsevier
Abstract Singlet oxygen (1 O 2) attracts much attention in persulfate-based advanced
oxidation processes (PS-AOPs), because of its wide pH tolerance and high selectivity …

Re-examining Fenton and Fenton-like reactions

D Meyerstein - Nature Reviews Chemistry, 2021 - nature.com
The Fenton and Fenton-like reactions are important in biology because they are a major
source of oxidative stress. The reactions also feature in advanced oxidation technologies to …

Unveiling singlet oxygen spin trapping in catalytic oxidation processes using in situ kinetic EPR analysis

JH Wu, F Chen, TH Yang… - Proceedings of the …, 2023 - National Acad Sciences
Singlet oxygen (1O2) plays a pivotal role in numerous catalytic oxidation processes utilized
in water purification and chemical synthesis. The spin-trapping method based on electron …

Bioinspired Trinuclear Copper Catalyst for Water Oxidation with a Turnover Frequency up to 20000 s–1

QF Chen, ZY Cheng, RZ Liao… - Journal of the American …, 2021 - ACS Publications
Solar-powered water splitting is a dream reaction for constructing an artificial photosynthetic
system for producing solar fuels. Natural photosystem II is a prototype template for research …

The Role of Bicarbonate-Based Electrolytes in H2O2 Production through Two-Electron Water Oxidation

TM Gill, L Vallez, X Zheng - ACS Energy Letters, 2021 - ACS Publications
Two-electron water oxidation (2e–WOR) is a promising route toward efficient production of a
valuable product in H2O2. Recent attention has focused on developing new electrocatalysts …

Efficient peroxymonosulfate activation by magnetic MoS2@ Fe3O4 for rapid degradation of free DNA bases and antibiotic resistance genes

C Nie, Y Hou, F Liu, Q Dong, Z Li, P Han, M Tong - Water Research, 2023 - Elsevier
Antibiotic resistance genes (ARGs) have become as emerging contaminant with great
concerns worldwide due to their threats to human health. It is thus urgent to develop …

Reaction of FeaqII with Peroxymonosulfate and Peroxydisulfate in the Presence of Bicarbonate: Formation of FeaqIV and Carbonate Radical Anions

A Kottapurath Vijay, V Marks, A Mizrahi… - Environmental …, 2023 - ACS Publications
Many advanced oxidation processes (AOPs) use Fenton-like reactions to degrade organic
pollutants by activating peroxymonosulfate (HSO5–, PMS) or peroxydisulfate (S2O82 …

Degradation of ciprofloxacin using heterogeneous Fenton catalysts derived from natural pyrite and rice straw biochar

F Sang, Z Yin, W Wang, E Almatrafi, Y Wang… - Journal of Cleaner …, 2022 - Elsevier
The increased use of antibiotics and the discharge of antibiotic wastewater have caused
severe pollution, and there is an urgent need for innovative treatment technologies. In this …

Engineered nanoconfinement accelerating spontaneous manganese-catalyzed degradation of organic contaminants

S Zhang, T Hedtke, L Wang, X Wang… - Environmental …, 2021 - ACS Publications
Manganese (III/IV) oxide minerals are known to spontaneously degrade organic pollutants in
nature. However, the kinetics are too slow to be useful for engineered water treatment …

Fenton-like Chemistry by a Copper(I) Complex and H2O2 Relevant to Enzyme Peroxygenase C–H Hydroxylation

B Kim, MT Brueggemeyer, WJ Transue… - Journal of the …, 2023 - ACS Publications
Lytic polysaccharide monooxygenases have received significant attention as catalytic
convertors of biomass to biofuel. Recent studies suggest that its peroxygenase activity (ie …