Hydrosilylation Reactions Catalyzed by Rhenium
Hydrosilylation is an important process, not only in the silicon industry to produce silicon
polymers, but also in fine chemistry. In this review, the development of rhenium-based …
polymers, but also in fine chemistry. In this review, the development of rhenium-based …
Oxo and imido complexes of rhenium and molybdenum in catalytic reductions
G Du, MM Abu-Omar - Current Organic Chemistry, 2008 - ingentaconnect.com
High oxidation state transition metal oxo and imido complexes are ubiquitous in catalytic
oxidations and oxygen atom transfer reactions. Recently these complexes, particularly those …
oxidations and oxygen atom transfer reactions. Recently these complexes, particularly those …
Enantioselective Reduction of Ketones and Imines Catalyzed by (CN‐Box)ReV–Oxo Complexes
The development and application of chiral, non‐racemic ReV–oxo complexes to the
enantioselective reduction of prochiral ketones is described. In addition to the …
enantioselective reduction of prochiral ketones is described. In addition to the …
Dehydrogenative coupling of alcohols and carboxylic acids with hydrosilanes catalyzed by a salen–Mn (V) complex
A Mn (V)–salen complex was found to be an effective catalyst for the dehydrogenative
coupling of hydroxyl groups with hydrosilane. The reaction conditions were optimized with …
coupling of hydroxyl groups with hydrosilane. The reaction conditions were optimized with …
A novel efficient and chemoselective method for the reduction of nitriles using the system silane/oxo-rhenium complexes
I Cabrita, AC Fernandes - Tetrahedron, 2011 - Elsevier
This work reports the reduction of nitriles to the corresponding primary amines with silanes
catalyzed by oxo-rhenium complexes. The catalytic system PhSiH3/ReIO2 (PPh3) 2 (10 …
catalyzed by oxo-rhenium complexes. The catalytic system PhSiH3/ReIO2 (PPh3) 2 (10 …
Mechanistic Aspects of Hydrosilylation Catalyzed by (ArN=)Mo(H)(Cl)(PMe3)3
AY Khalimon, O Sherbrooke, E Peterson… - Inorganic …, 2012 - ACS Publications
The reaction of (ArN=) MoCl2 (PMe3) 3 (Ar= 2, 6-diisopropylphenyl) with L-Selectride gives
the hydrido-chloride complex (ArN=) Mo (H)(Cl)(PMe3) 3 (2). Complex 2 was found to …
the hydrido-chloride complex (ArN=) Mo (H)(Cl)(PMe3) 3 (2). Complex 2 was found to …
Scope and mechanistic studies of catalytic hydrosilylation with a high-valent nitridoruthenium (VI)
S Abbina, S Bian, C Oian, G Du - ACS Catalysis, 2013 - ACS Publications
Hydrosilylation catalyzed by a high-valent nitridoruthenium (VI) compound,[RuN
(saldach)(CH3OH)]+[ClO4]−(1, where saldach is the dianion of racemic N, N′-cyclohexan …
(saldach)(CH3OH)]+[ClO4]−(1, where saldach is the dianion of racemic N, N′-cyclohexan …
Rhenium-Catalyzed Reduction of Carboxylic Acids with Hydrosilanes
Re2 (CO) 10 efficiently catalyzes the direct reduction of various carboxylic acids under mild
conditions (rt, irradiation 350 or 395 nm). While aliphatic carboxylic acids were readily …
conditions (rt, irradiation 350 or 395 nm). While aliphatic carboxylic acids were readily …
An efficient method for the preparation of oxo molybdenum salalen complexes and their unusual use as hydrosilylation catalysts
JE Ziegler, G Du, PE Fanwick… - Inorganic chemistry, 2009 - ACS Publications
A number of molybdenum (VI) dioxo salalen complexes were prepared from the reaction of
Mo (CO) 6 and salen ligands containing bulky substituents, providing a novel and facile …
Mo (CO) 6 and salen ligands containing bulky substituents, providing a novel and facile …
Comparison of molybdenum and rhenium oxo bis-pyrazine-dithiolene complexes–in search of an alternative metal centre for molybdenum cofactor models
N Chrysochos, M Ahmadi, S Wahlefeld, Y Rippers… - Dalton …, 2019 - pubs.rsc.org
A pair of structurally precise analogues of molybdenum and rhenium complexes,[Et4N]/K2
[MoO (prdt) 2] and K [ReO (prdt) 2](prdt= pyrazine-2, 3-dithiolene), were synthesized. These …
[MoO (prdt) 2] and K [ReO (prdt) 2](prdt= pyrazine-2, 3-dithiolene), were synthesized. These …