On the present and future of dissolution-DNP

JH Ardenkjaer-Larsen - Journal of Magnetic Resonance, 2016 - Elsevier
Dissolution-DNP is a method to create solutions of molecules with nuclear spin polarization
close to unity. The many orders of magnitude signal enhancement have enabled many new …

Practical dissolution dynamic nuclear polarization

SJ Elliott, Q Stern, M Ceillier, T El Daraï… - Progress in Nuclear …, 2021 - Elsevier
This review article intends to provide insightful advice for dissolution-dynamic nuclear
polarization in the form of a practical handbook. The goal is to aid research groups to …

Efficient dynamic nuclear polarization at 800 MHz/527 GHz with trityl‐nitroxide biradicals

G Mathies, MA Caporini, VK Michaelis… - Angewandte Chemie …, 2015 - Wiley Online Library
Cross‐effect (CE) dynamic nuclear polarization (DNP) is a rapidly developing technique that
enhances the signal intensities in magic‐angle spinning (MAS) NMR spectra. We report CE …

Overhauser effects in insulating solids

TV Can, MA Caporini, F Mentink-Vigier… - The Journal of …, 2014 - pubs.aip.org
BACKGROUND Part of our results (vide infra) share a characteristic feature with the
Overhauser effect in solution where an enhancement is observed around the electron …

BDPA-nitroxide biradicals tailored for efficient dynamic nuclear polarization enhanced solid-state NMR at magnetic fields up to 21.1 T

D Wisser, G Karthikeyan, A Lund… - Journal of the …, 2018 - ACS Publications
Dynamic nuclear polarization (DNP) solid-state nuclear magnetic resonance (NMR) has
developed into an invaluable tool for the investigation of a wide range of materials …

Hyperpolarized magnetic resonance as a sensitive detector of metabolic function

A Comment, ME Merritt - Biochemistry, 2014 - ACS Publications
Hyperpolarized magnetic resonance allows for noninvasive measurements of biochemical
reactions in vivo. Although this technique provides a unique tool for assaying enzymatic …

Cryogen‐free dissolution dynamic nuclear polarization polarizer operating at 3.35 T, 6.70 T, and 10.1 T

JH Ardenkjær‐Larsen, S Bowen… - Magnetic …, 2019 - Wiley Online Library
Purpose A novel dissolution dynamic nuclear polarization (dDNP) polarizer platform is
presented. The polarizer meets a number of key requirements for in vitro, preclinical, and …

Application and methodology of dissolution dynamic nuclear polarization in physical, chemical and biological contexts

S Jannin, JN Dumez, P Giraudeau… - Journal of Magnetic …, 2019 - Elsevier
Dissolution dynamic nuclear polarization (d-DNP) is a versatile method to enhance nuclear
magnetic resonance (NMR) spectroscopy. It boosts signal intensities by four to five orders of …

Hyperpolarization via dissolution dynamic nuclear polarization: new technological and methodological advances

AC Pinon, A Capozzi, JH Ardenkjær-Larsen - … Resonance Materials in …, 2021 - Springer
Dissolution-DNP is a method to boost liquid-state NMR sensitivity by several orders of
magnitude. The technique consists in hyperpolarizing samples by solid-state dynamic …

Efficient cross-effect dynamic nuclear polarization without depolarization in high-resolution MAS NMR

F Mentink-Vigier, G Mathies, Y Liu, AL Barra… - Chemical …, 2017 - pubs.rsc.org
Dynamic nuclear polarization (DNP) has the potential to enhance the sensitivity of magic-
angle spinning (MAS) NMR by many orders of magnitude and therefore to revolutionize …