Evans' Chiral Auxiliary‐Based Asymmetric Synthetic Methodology and Its Modern Extensions
LY Chen, PQ Huang - European Journal of Organic Chemistry, 2024 - Wiley Online Library
Although the asymmetric catalysis has made a spurt of progress, the use of chiral auxiliaries
remains crucial in asymmetric synthesis due to both the reliability and versatility of the …
remains crucial in asymmetric synthesis due to both the reliability and versatility of the …
Recent Advances in the Development of Enantiopure BODIPYs and Some Related Enantiomeric Compounds
During the process of developing smart chiroptical luminophores, small chiral organic dyes
have emerged as candidates of utmost importance. In this regard, the chiral variants of …
have emerged as candidates of utmost importance. In this regard, the chiral variants of …
Three-Component Gold (I)-Catalyzed Alkoxyvinylation
LA Hammarback, T Medina-Gil, A Sadurní… - Organic …, 2024 - ACS Publications
Acetylene has been underexploited despite being a highly valuable feedstock for chemical
synthesis. We have developed the first true gold (I)-catalyzed intermolecular three …
synthesis. We have developed the first true gold (I)-catalyzed intermolecular three …
Azobenzene-Integrated NHC Ligands: A Versatile Platform for Visible-Light-Switchable Metal Catalysis
M Rölz, B Butschke, B Breit - Journal of the American Chemical …, 2024 - ACS Publications
A new class of photoswitchable NHC ligands, named azImBA, has been developed by
integrating azobenzene into a previously unreported imidazobenzoxazol-1-ylidene …
integrating azobenzene into a previously unreported imidazobenzoxazol-1-ylidene …
Microporous Polymeric Networks Containing a Long-Term Stable AuI Catalyst for Enyne Cyclization
S Rico-Martínez, A Ruiz, B López-Iglesias… - ACS Applied Polymer …, 2024 - ACS Publications
Two microporous polymer networks having a confined AuI carbene catalyst were obtained
and tested for the skeletal rearrangement of enynes. These catalysts were obtained from …
and tested for the skeletal rearrangement of enynes. These catalysts were obtained from …
Gold/HNTf2-Cocatalyzed Asymmetric Annulation of Diazo-Alkynes: Divergent Construction of Atropisomeric Biaryls and Arylquinones
YB Wang, W Liu, T Li, Y Lu, YT Yu, HT Liu… - Journal of the …, 2024 - ACS Publications
Due to the inherent challenges posed by the linear coordination of gold (I) complexes,
asymmetric gold-catalyzed processes remain challenging, particularly in the atroposelective …
asymmetric gold-catalyzed processes remain challenging, particularly in the atroposelective …
Fluorinated Biphenyl Phosphine Ligands for Accelerated [Au (I)]-Catalysis
Fluorinated JohnPhos-type ligands are proposed as accelerating tools in homogeneous
gold (I) catalysis, with PedroPhosAuC l (Cat1) as the most efficient one. The ligands as well …
gold (I) catalysis, with PedroPhosAuC l (Cat1) as the most efficient one. The ligands as well …
Asymmetric electrosynthesis: emerging catalytic strategies and mechanistic insights
X Jiang, C Zou, W Zhuang, R Li, Y Yang, C Yang… - Green …, 2025 - pubs.rsc.org
Asymmetric electrosynthesis is an innovative approach that combines electrochemistry with
asymmetric catalysis, enabling the selective synthesis of chiral molecules. Advancements in …
asymmetric catalysis, enabling the selective synthesis of chiral molecules. Advancements in …
Electrochemical selenocyclization of N-alkyl anilines: Access to 3-selenyl quinolines
L Zhao, H Li, M Peng, S Wang, M Li, Q Zhao, W Huang… - Tetrahedron, 2024 - Elsevier
Selenyl quinolines are an important class of compounds that have found significant
applications in pharmaceuticals and synthetic chemistry. Herein, we describe an …
applications in pharmaceuticals and synthetic chemistry. Herein, we describe an …
Electrochemical Selenocyclization of N-(2-Alkyle) Anilines: Access to 3-Selenylquinolines
F Ji, L Zhao, H Li, M Peng, S Wang, M Li… - Available at SSRN … - papers.ssrn.com
Selenylquinolines are an important class of compounds that have found significant
applications in pharmaceuticals and synthetic chemistry. Herein, we describe an …
applications in pharmaceuticals and synthetic chemistry. Herein, we describe an …