Metal‐Free Carbon Materials for CO2 Electrochemical Reduction

X Duan, J Xu, Z Wei, J Ma, S Guo, S Wang… - Advanced …, 2017 - Wiley Online Library
The rapid increase of the CO2 concentration in the Earth's atmosphere has resulted in
numerous environmental issues, such as global warming, ocean acidification, melting of the …

Catalytic transformation of CO 2 into C1 chemicals using hydrosilanes as a reducing agent

Y Zhang, T Zhang, S Das - Green Chemistry, 2020 - pubs.rsc.org
Utilization of CO2 for the synthesis of fine chemicals and pharmaceuticals has attracted
tremendous attention. In fact, reductive transformation of CO2 is also an interesting …

Utilization of CO2 as a C1 Building Block for Catalytic Methylation Reactions

Y Li, X Cui, K Dong, K Junge, M Beller - ACS Catalysis, 2017 - ACS Publications
Developing new synthetic approaches for benign CO2 utilization is of current interest. In this
respect, reductive alkylations using N-or C-based nucleophiles to give the corresponding …

Synthesis, structure, and catalysis of palladium complexes bearing a group 13 metalloligand: remarkable effect of an aluminum-metalloligand in hydrosilylation of CO2

J Takaya, N Iwasawa - Journal of the American Chemical Society, 2017 - ACS Publications
Efficient synthesis and catalysis of a series of palladium complexes having a group 13
metalloligand (Al, Ga, In) are reported utilizing 6, 6 ″-bis (phosphino) terpyridine as a new …

Selective formylation and methylation of amines using carbon dioxide and hydrosilane catalyzed by alkali-metal carbonates

C Fang, C Lu, M Liu, Y Zhu, Y Fu, BL Lin - ACS Catalysis, 2016 - ACS Publications
The formylation and methylation of amines with carbon dioxide and hydrosilanes are
emerging yet important types of transformations for CO2. Catalytic methods effective for both …

Boron-mediated activation of carbon dioxide

S Bontemps - Coordination Chemistry Reviews, 2016 - Elsevier
Carbon dioxide is a very abundant molecule that is used as building block by nature. It
would be a sustainable resource for our carbon-based societies if we could emulate nature …

From CO 2 activation to catalytic reduction: a metal-free approach

P Sreejyothi, SK Mandal - Chemical Science, 2020 - pubs.rsc.org
Over exploitation of natural resources and human activities are relentlessly fueling the
emission of CO2 in the atmosphere. Accordingly, continuous efforts are required to find …

Zinc and magnesium catalysts for the hydrosilylation of carbon dioxide

M Rauch, G Parkin - Journal of the American Chemical Society, 2017 - ACS Publications
The terminal zinc and magnesium hydride compounds,[κ3-TismPriBenz] ZnH and
[TismPriBenz] MgH, which feature the tris [(1-isopropylbenzimidazol-2-yl) dimethylsilyl] …

N-Heterocyclic Carbene Moiety in Highly Porous Organic Hollow Nanofibers for Efficient CO2 Conversions: A Comparative Experimental and Theoretical Study

S Bhattacharjee, A Tripathi, R Chatterjee, R Thapa… - ACS …, 2024 - ACS Publications
Global warming and climate change are two severe environmental dangers brought on by
the steady rise in the carbon dioxide (CO2) concentration in the atmosphere. Thus, in order …

Carbon Dioxide Reduction to Methylamines under Metal‐Free Conditions

E Blondiaux, J Pouessel, T Cantat - Angewandte Chemie, 2014 - Wiley Online Library
The first metal‐free catalysts are reported for the methylation of amines with carbon dioxide.
Proazaphosphatrane superbases prove to be highly active catalysts in the reductive …