A review on research progress in the direct synthesis of hydrogen peroxide from hydrogen and oxygen: noble-metal catalytic method, fuel-cell method and plasma …

Y Yi, L Wang, G Li, H Guo - Catalysis Science & Technology, 2016 - pubs.rsc.org
Hydrogen peroxide (H2O2) as a highly efficient and green oxidant has become one of the
100 most important chemicals in the world. Some current research progress in the direct …

Advanced development strategy of nano catalyst and DFT calculations for direct synthesis of hydrogen peroxide

GH Han, SH Lee, SY Hwang… - Advanced Energy …, 2021 - Wiley Online Library
Hydrogen peroxide is a simple oxidizing agent. Its environmental benignness and
effectiveness have led to a continuous increase in its use and production. Anthraquinone …

Active sites and mechanisms for H2O2 decomposition over Pd catalysts

A Plauck, EE Stangland, JA Dumesic… - Proceedings of the …, 2016 - National Acad Sciences
A combination of periodic, self-consistent density functional theory (DFT-GGA-PW91)
calculations, reaction kinetics experiments on a SiO2-supported Pd catalyst, and mean-field …

Adsorption of SF6 decomposition components over Pd (1 1 1): A density functional theory study

D Liu, Y Gui, C Ji, C Tang, Q Zhou, J Li, X Zhang - Applied Surface Science, 2019 - Elsevier
This work studies the adsorption properties of Pd (1 1 1) surface to various SF 6
decomposition components (H 2 S, SO 2, SOF 2, and SO 2 F 2). Due to the affluent active d …

Efficient Direct H2O2 Synthesis Enabled by PdPb Nanorings via Inhibiting the O–O Bond Cleavage in O2 and H2O2

K Cao, H Yang, S Bai, Y Xu, C Yang, Y Wu, M Xie… - ACS …, 2021 - ACS Publications
Direct H2O2 synthesis (DHS) from H2 and O2 is a promising process in industry; however,
challenges related to poor H2O2 selectivity and low H2O2 yield remain. We report here that …

The origin of active sites for direct synthesis of H2O2 on Pd/TiO2 catalysts: Interfaces of Pd and PdO domains

L Ouyang, P Tian, G Da, XC Xu, C Ao, T Chen, R Si… - Journal of …, 2015 - Elsevier
Direct synthesis of H 2 O 2 from H 2 and O 2 on Pd/TiO 2 catalysts has been systematically
studied to gain understanding of the origin of active sites. For the first time, the structure of …

Microkinetic Modeling with Size-Dependent and Adsorbate–Adsorbate Interactions for the Direct Synthesis of H2O2 over Pd Nanoparticles

J Zhao, Z Yao, RJ Bunting, P Hu, J Wang - ACS Catalysis, 2023 - ACS Publications
As a bottleneck in the direct synthesis of hydrogen peroxide, the development of an efficient
palladium-based catalyst has garnered great attention. However, elusive active centers and …

Facet dependence of electrocatalytic furfural hydrogenation on palladium nanocrystals

W Zhang, Y Shi, Y Yang, J Tan, Q Gao - Chinese Journal of Catalysis, 2022 - Elsevier
Electrocatalytic hydrogenation (ECH) offers a sustainable route for the conversion of
biomass-derived feedstocks under ambient conditions; however, an atomic-level …

Revealing the steric effects of cobalt porphyrin on the selectivity of oxygen reduction reaction

X Chen, Y Dai, H Zhang, X Zhao - Colloids and Surfaces A …, 2023 - Elsevier
It is well known that auxiliary groups have an important effect on the selectivity of Co
porphyrins for oxygen reduction reaction (ORR). In this paper, the catalytic performance of …

Facet effect of single-crystalline Pd nanocrystals for aerobic oxidation of 5-hydroxymethyl-2-furfural

D Lei, K Yu, MR Li, Y Wang, Q Wang, T Liu, P Liu… - ACS …, 2017 - ACS Publications
Single-crystalline Pd nanocrystals enclosed by {111} or {100} facets with controllable sizes
were synthesized and originally employed as catalysts in the aerobic oxidation of 5 …