Luminescent ionic transition‐metal complexes for light‐emitting electrochemical cells

RD Costa, E Ortí, HJ Bolink, F Monti… - Angewandte Chemie …, 2012 - Wiley Online Library
Higher efficiency in the end‐use of energy requires substantial progress in lighting concepts.
All the technologies under development are based on solid‐state electroluminescent …

Photofunctional triplet excited states of cyclometalated Ir (III) complexes: beyond electroluminescence

Y You, W Nam - Chemical Society Reviews, 2012 - pubs.rsc.org
The development of cyclometalated Ir (III) complexes has enabled important breakthroughs
in electroluminescence because such complexes permit the efficient population of triplet …

Excited-state engineering in heteroleptic ionic iridium (III) complexes

F Monti, A Baschieri, L Sambri… - Accounts of Chemical …, 2021 - ACS Publications
Conspectus Iridium (III) complexes have assumed a prominent role in the areas of
photochemistry and photophysics due to the peculiar properties of both the metal itself and …

Phosphorescent iridium (III)-bis-N-heterocyclic carbene complexes as mitochondria-targeted theranostic and photodynamic anticancer agents

Y Li, CP Tan, W Zhang, L He, LN Ji, ZW Mao - Biomaterials, 2015 - Elsevier
Mitochondria-targeted compounds represent a promising approach to target tumors
selectively and overcome resistance to current anticancer therapies. In this work, three …

Over the LEC rainbow: Colour and stability tuning of cyclometallated iridium (III) complexes in light-emitting electrochemical cells

CE Housecroft, EC Constable - Coordination Chemistry Reviews, 2017 - Elsevier
This review surveys the design of cyclometallated iridium (III) complexes for applications in
light-emitting electrochemical cells (LECs). Typical iridium-containing ionic transition metal …

A solid chelating ligand: periodic mesoporous organosilica containing 2, 2′-bipyridine within the pore walls

M Waki, Y Maegawa, K Hara, Y Goto… - Journal of the …, 2014 - ACS Publications
Synthesis of a solid chelating ligand for the formation of efficient heterogeneous catalysts is
highly desired in the fields of organic transformation and solar energy conversion. Here, we …

Cyclometalated Ir (III) complexes towards blue-emissive dopant for organic light-emitting diodes: fundamentals of photophysics and designing strategies

S Lee, WS Han - Inorganic Chemistry Frontiers, 2020 - pubs.rsc.org
The main difficulties hindering development of a deep-blue phosphorescent cyclometalated
Ir (III) complex are insufficient colour purity, ie, failure to achieve ideal Commission …

Iridium(III) 1-Phenylisoquinoline Complexes as a Photosensitizer for Photocatalytic CO2 Reduction: A Mixed System with a Re(I) Catalyst and a Supramolecular …

Y Kuramochi, O Ishitani - Inorganic chemistry, 2016 - ACS Publications
An Ir (III) complex with 1-phenylisoquinoline (piq) ligands [Ir (piq) 2 (dmb)]+(Ir, dmb= 4, 4′-
dimethyl-2, 2′-bipyridine) exhibited strong absorption in the visible region, and the lifetime …

A comprehensive survey of cationic iridium (III) complexes bearing nontraditional ligand chelation motifs

S Ladouceur, E Zysman‐Colman - European Journal of …, 2013 - Wiley Online Library
The useful optoelectronic properties of cationic iridium (III) complexes have been exploited
in diverse applications, from visual displays to biological probes to analytical sensors. It is …

Charged bis-cyclometalated iridium (III) complexes with carbene-based ancillary ligands

F Monti, F Kessler, M Delgado, J Frey… - Inorganic …, 2013 - ACS Publications
Charged cyclometalated (C∧ N) iridium (III) complexes with carbene-based ancillary
ligands are a promising family of deep-blue phosphorescent compounds. Their emission …