Scanning probe microscopy

K Bian, C Gerber, AJ Heinrich, DJ Müller… - Nature Reviews …, 2021 - nature.com
Scanning probe microscopy (SPM), a key invention in nanoscience, has by now been
extended to a wide spectrum of basic and applied fields. Its application to basic science led …

Controlling a chemical coupling reaction on a surface: tools and strategies for on-surface synthesis

S Clair, DG de Oteyza - Chemical reviews, 2019 - ACS Publications
On-surface synthesis is appearing as an extremely promising research field aimed at
creating new organic materials. A large number of chemical reactions have been …

An sp-hybridized molecular carbon allotrope, cyclo [18] carbon

K Kaiser, LM Scriven, F Schulz, P Gawel, L Gross… - Science, 2019 - science.org
Carbon allotropes built from rings of two-coordinate atoms, known as cyclo [n] carbons, have
fascinated chemists for many years, but until now they could not be isolated or structurally …

Covalent on-surface polymerization

L Grill, S Hecht - Nature Chemistry, 2020 - nature.com
With the rapid development of scanning probe microscopy, it has become possible to study
polymerization processes on suitable surfaces at the atomic level and in real space. In the …

Clip chemistry: diverse (bio)(macro) molecular and material function through breaking covalent bonds

P Shieh, MR Hill, W Zhang, SL Kristufek… - Chemical …, 2021 - ACS Publications
In the two decades since the introduction of the “click chemistry” concept, the toolbox of “click
reactions” has continually expanded, enabling chemists, materials scientists, and biologists …

Quantum nanomagnets in on-surface metal-free porphyrin chains

Y Zhao, K Jiang, C Li, Y Liu, G Zhu, M Pizzochero… - Nature Chemistry, 2023 - nature.com
Unlike classic spins, quantum magnets are spin systems that interact via the exchange
interaction and exhibit collective quantum behaviours, such as fractional excitations …

Reactions in single-molecule junctions

H Chen, C Jia, X Zhu, C Yang, X Guo… - Nature Reviews …, 2023 - nature.com
Developing new materials is a long-standing goal that extends across the fields of synthesis,
catalysis, nanotechnology and materials science. Transforming one compound or material …

Supramolecular assemblies on surfaces: nanopatterning, functionality, and reactivity

DP Goronzy, M Ebrahimi, F Rosei, Arramel, Y Fang… - ACS …, 2018 - ACS Publications
Understanding how molecules interact to form large-scale hierarchical structures on
surfaces holds promise for building designer nanoscale constructs with defined chemical …

Selectivity in single-molecule reactions by tip-induced redox chemistry

F Albrecht, S Fatayer, I Pozo, I Tavernelli, J Repp… - Science, 2022 - science.org
Controlling selectivity of reactions is an ongoing quest in chemistry. In this work, we
demonstrate reversible and selective bond formation and dissociation promoted by tip …

Harnessing electrostatic catalysis in single molecule, electrochemical and chemical systems: a rapidly growing experimental tool box

S Ciampi, N Darwish, HM Aitken, I Díez-Pérez… - Chemical Society …, 2018 - pubs.rsc.org
Static electricity is central to many day-to-day practical technologies, from separation
methods in the recycling of plastics to transfer inks in photocopying, but the exploration of …