This review summarizes the advancements in rhodium-catalyzed asymmetric C–H
functionalization reactions during the last two decades. Parallel to the rapidly developed …

The molecular design of polymer interfaces has been key for advancing electrochemical
separation processes. Precise control of molecular interactions at electrochemical interfaces …

Satoh–Miura reaction is an important method for extending π‐systems by forging multi‐
substituted benzene rings via double aryl C− H activation and annulation with alkynes …

Asymmetric ring-opening of 7-oxabenzonorbornadienes is achieved via Co-catalyzed indole
C–H functionalization. The utilization of chiral Co-catalyst consisting of a binaphthyl-derived …

A wide range of Cu (II)-catalyzed C–H activation reactions have been realized since 2006,
however, whether a C–H metalation mechanism similar to Pd (II)-catalyzed C–H activation …

Spiro cyclopentadienyl rhodium (SCpRh) complexes are powerful catalysts for promoting
asymmetric C–H functionalization reactions. However, the application of chiral SCp ligands …

Macrocycles incorporating conformationally defined indoles are widely found in bioactive
natural products. However, the catalytic enantioselective synthesis of planar-chiral indoles …

N–N axially chiral biaryls represent a rarely explored class of atropisomeric compounds. We
hereby report rhodium-catalyzed enantioselective [4+ 2] oxidative annulation of internal …

The atroposelective direct C–H alkylation of heterobiaryls with simple alkenes represents a
challenging and underexplored frontier. Herein we report an iridium (I)-catalyzed …

During the past decades, in synthetic organic chemistry, directing‐group‐assisted C− H
functionalization is found to be a key tool for the expedient and site‐selective construction of …