First-row transition metal (de) hydrogenation catalysis based on functional pincer ligands

L Alig, M Fritz, S Schneider - Chemical reviews, 2018 - ACS Publications
The use of 3d metals in de/hydrogenation catalysis has emerged as a competitive field with
respect to “traditional” precious metal catalyzed transformations. The introduction of …

Liquid organic hydrogen carriers for transportation and storing of renewable energy–Review and discussion

PT Aakko-Saksa, C Cook, J Kiviaho, T Repo - Journal of Power Sources, 2018 - Elsevier
Transition to renewable energy systems is essential to achieve the climate change
mitigation targets. However, the timing and the regions of the production and consumption of …

Homogeneous transition metal catalysis of acceptorless dehydrogenative alcohol oxidation: applications in hydrogen storage and to heterocycle synthesis

RH Crabtree - Chemical Reviews, 2017 - ACS Publications
The different types of acceptorless alcohol dehydrogenation (AAD) reactions are discussed,
followed by the catalysts and mechanisms involved. Special emphasis is put on the common …

Manganese-Catalyzed Environmentally Benign Dehydrogenative Coupling of Alcohols and Amines to Form Aldimines and H2: A Catalytic and Mechanistic Study

A Mukherjee, A Nerush, G Leitus… - Journal of the …, 2016 - ACS Publications
The catalytic dehydrogenative coupling of alcohols and amines to form aldimines represents
an environmentally benign methodology in organic chemistry. This has been accomplished …

[HTML][HTML] Homogeneously catalyzed acceptorless dehydrogenation of alcohols: A progress report

M Trincado, J Bösken, H Grützmacher - Coordination Chemistry Reviews, 2021 - Elsevier
Catalytic dehydrogenation of alcohols represents an attractive approach for future
applications as hydrogen storage systems and clean synthesis of fine chemicals. Herein, an …

Nickel and iron pincer complexes as catalysts for the reduction of carbonyl compounds

S Chakraborty, P Bhattacharya, H Dai… - Accounts of Chemical …, 2015 - ACS Publications
Conspectus The reductions of aldehydes, ketones, and esters to alcohols are important
processes for the synthesis of chemicals that are vital to our daily life, and the reduction of …

Divergent Coupling of Alcohols and Amines Catalyzed by Isoelectronic Hydride MnI and FeII PNP Pincer Complexes

M Mastalir, M Glatz, N Gorgas, B Stöger… - … A European Journal, 2016 - Wiley Online Library
Herein, we describe an efficient coupling of alcohols and amines catalyzed by well‐defined
isoelectronic hydride MnI and FeII complexes, which are stabilized by a PNP ligand based …

Manganese pincer complexes for the base-free, acceptorless dehydrogenative coupling of alcohols to esters: development, scope, and understanding

DH Nguyen, X Trivelli, F Capet, JF Paul… - ACS …, 2017 - ACS Publications
Aliphatic PNP pincer-supported earth-abundant manganese (I) dicarbonyl complexes
behave as effective catalysts for the acceptorless dehydrogenative coupling of a wide range …

Advancement in photocatalytic acceptorless dehydrogenation reactions: Opportunity and challenges for sustainable catalysis

PK Verma - Coordination Chemistry Reviews, 2022 - Elsevier
Dehydrogenation reactions are the challenging and thermodynamically unfavorable.
Traditionally, high temperature and pressure conditions, excess of oxidants and sacrificial …

Transfer hydrogenation of alkenes using ethanol catalyzed by a NCP pincer iridium complex: scope and mechanism

Y Wang, Z Huang, X Leng, H Zhu, G Liu… - Journal of the …, 2018 - ACS Publications
The first general catalytic approach to effecting transfer hydrogenation (TH) of unactivated
alkenes using ethanol as the hydrogen source is described. A new NCP-type pincer iridium …