A dual pH‐and light‐responsive spiropyran‐based surfactant: Investigations on its switching behavior and remote control over emulsion stability

M Reifarth, M Bekir, AM Bapolisi, E Titov… - Angewandte Chemie …, 2022 - Wiley Online Library
A cationic surfactant containing a spiropyran unit is prepared exhibiting a dual‐responsive
adjustability of its surface‐active characteristics. The switching mechanism of the system …

Compartmentalized Polyampholyte Microgels by Depletion Flocculation and Coacervation of Nanogels in Emulsion Droplets

HF Mathews, MI Pieper, SH Jung… - Angewandte Chemie …, 2023 - Wiley Online Library
In pH‐responsive drug carriers, the distribution of charges has been proven to affect delivery
efficiency but is difficult to control and verify. Herein, we fabricate polyampholyte nanogel‐in …

[HTML][HTML] FLIM nanoscopy resolves the structure and preferential adsorption in the co-nonsolvency of PNIPAM microgels in methanol-water

SP Centeno, K Nothdurft, AS Klymchenko… - Journal of Colloid and …, 2025 - Elsevier
Polymer microgels are swollen macromolecular networks with a typical size of hundred of
nanometers to several microns that show an extraordinary open and responsive architecture …

Adsorption Kinetics of a Photosensitive Surfactant Inside Microgels

A Sharma, SH Jung, N Lomadze, A Pich… - …, 2021 - ACS Publications
Here, we investigate the kinetics of adsorption and desorption of a cationic photosensitive
azobenzene-containing surfactant within anionic microgels in the dark and under …

Photoswitchable Surfactants–Are there Alternatives to Azobenzene‐Based Systems?

M Bekir, J Gurke, M Reifarth - ChemSystemsChem, 2024 - Wiley Online Library
Owing to their property to alter their surface‐activity upon the irradiation with light,
photoswitchable surfactants have gained tremendous interest in colloidal science. Their …

Catalyzed Henry Reaction by Compartmentalized Copper‐Pyrazolyl‐Complex Modified Microgels

F Grabowski, F Fink, WS Schier… - Advanced Functional …, 2024 - Wiley Online Library
Compartmentalization of homogeneous catalysts enhances their catalytic performance and
can even increase the selectivity. Microgels can serve as smart catalyst carrier systems …

Photo-and thermo-responsive microgels with supramolecular crosslinks for wavelength tunability of the volume phase transition temperature

W Liang, CG Lopez, W Richtering… - Physical Chemistry …, 2022 - pubs.rsc.org
Functional microgels have powerful applications, especially due to their quick
responsiveness to different external stimuli such as temperature, pH, ionic strength, solvent …

Making microgels photo-responsive by complexation with a spiropyran surfactant

A Sharma, YD Gordievskaya, N Lomadze, M Bekir… - Soft Matter, 2023 - pubs.rsc.org
We report on triggering of p (NIPAM-AA) microgels' photo-responsiveness by making
complexes with a spiropyran (SP) containing surfactant. Being dissolved in water, the SP …

Selective Segregation of Thermo‐Responsive Microgels via Microfluidic Technology

A Sharma, F Rohne, D Vasquez‐Muñoz… - Small …, 2024 - Wiley Online Library
Separation of equally sized particles distinguished solely by material properties remains still
a very challenging task. Here a simple separation of differently charged, thermo‐responsive …

Investigation of morphology and volume phase transition of supramacromolecular microgels by NMR spectroscopy and quartz crystal microbalance

S Braun, M Santi, DE Demco, I Litzen… - Journal of Polymer …, 2024 - Wiley Online Library
Microgels have a wide range of applications, from catalysis to biomedical applications such
as drug delivery in dispersion, or as surface‐attached materials to improve the …