Prodrugs of phosphonates and phosphates: crossing the membrane barrier
A substantial portion of metabolism involves transformation of phosphate esters, including
pathways leading to nucleotides and oligonucleotides, carbohydrates, isoprenoids and …
pathways leading to nucleotides and oligonucleotides, carbohydrates, isoprenoids and …
Recent advances in photocatalytic C–S/P–S bond formation via the generation of sulfur centered radicals and functionalization
Thioyl and sulfonyl radicals are usually produced from various thiols and sulfonyl derivatives
in high efficiency by single-electron-transfer (SET) oxidation. The generated sulfur …
in high efficiency by single-electron-transfer (SET) oxidation. The generated sulfur …
Visible-light-driven multicomponent reactions to access S-alkyl phosphorothioates using elemental sulfur as the sulfur source
C Qu, R Liu, Z Wang, Y Lv, H Yue, W Wei - Green Chemistry, 2022 - pubs.rsc.org
A metal-free and unprecedented strategy has been established for the construction of S-
alkyl phosphorothioates through visible-light-driven four-component reactions of α …
alkyl phosphorothioates through visible-light-driven four-component reactions of α …
Cs2CO3‐Catalyzed Aerobic Oxidative Cross‐Dehydrogenative Coupling of Thiols with Phosphonates and Arenes
An efficient Cs2CO3‐catalyzed oxidative coupling of thiols with phosphonates and arenes
that uses molecular oxygen as the oxidant is described. These reactions provide not only a …
that uses molecular oxygen as the oxidant is described. These reactions provide not only a …
Visible-light-induced four-component difunctionalization of alkenes to construct phosphorodithioate-containing quinoxalin-2 (1H)-ones
XM Chen, L Song, J Pan, F Zeng, Y Xie, W Wei… - Chinese Chemical …, 2024 - Elsevier
A facile visible-light-induced 1, 2, 3, 5-tetrakis (carbazol-9-yl)-4, 6-dicyanobenzene (4CzIPN)
catalyzed four-component reaction of alkenes, quinoxalin-2 (1H)-ones, P 4 S 10 and …
catalyzed four-component reaction of alkenes, quinoxalin-2 (1H)-ones, P 4 S 10 and …
Efficient Pd-catalyzed dehydrogenative coupling of P (O) H with RSH: A precise construction of P (O)–S bonds
Y Zhu, T Chen, S Li, S Shimada… - Journal of the American …, 2016 - ACS Publications
A Pd-catalyzed dehydrogenative phosphorylation of thiols is developed. A variety of thiols
dehydrogenatively couple readily with all three kinds of P (O)–H compounds, ie, H …
dehydrogenatively couple readily with all three kinds of P (O)–H compounds, ie, H …
Metal-free visible-light-mediated oxidative cross-coupling of thiols with P (O) H compounds using air as the oxidant
JG Sun, H Yang, P Li, B Zhang - Organic letters, 2016 - ACS Publications
Visible light along with 5 mol% of rose bengal catalyzes the direct S–P (O) coupling between
thiols and P (O) H compounds in the presence of air as the green oxidant. The protocol is …
thiols and P (O) H compounds in the presence of air as the green oxidant. The protocol is …
Electrochemical phosphorothiolation and 1, 4-S→ C phospho-Fries rearrangement: controlled access to phosphorothiolated and mercapto-phosphono substituted …
X Liu, W Jiang, C Huang, S Ma, Q Wang… - Organic Chemistry …, 2023 - pubs.rsc.org
An unprecedented electrochemically regioselective C–H phosphorothiolation and S-to C-[1,
4] phosphoryl migration involving indolizines, elemental sulfur, and H-phosphonates in an …
4] phosphoryl migration involving indolizines, elemental sulfur, and H-phosphonates in an …
Copper-Catalyzed Fluoroalkylphosphorothiolation of Alkynes for the Synthesis of (E)-β-Fluoroalkyl Vinyl Phosphorothioates
S Shi, H Chen, M Zhao, S Yang, P Li, X Wang… - Organic …, 2023 - ACS Publications
A convenient copper-catalyzed three-component radical-based
fluoroalkylphosphorothiolation of terminal alkynes with (i PrO) 2P (O) SH and …
fluoroalkylphosphorothiolation of terminal alkynes with (i PrO) 2P (O) SH and …
Gold-catalyzed alkenylation and arylation of phosphorothioates
Reported herein is the ligand-enabled gold-catalyzed alkenylation and arylation of
phosphorothioates using alkenyl and aryl iodides. Mechanistic studies revealed a crucial …
phosphorothioates using alkenyl and aryl iodides. Mechanistic studies revealed a crucial …