The photoactivation of electron donor–acceptor complexes has emerged as a sustainable,
selective and versatile strategy for the generation of radical species. However, when it …

The Nef reaction (nitro to carbonyl group conversion) and related Meyer reaction are among
the key transformations of aliphatic nitro compounds. The interrupted versions of these …

Stapling has emerged as a powerful technique in peptide chemistry. It enables precise
control over peptide conformation leading to enhanced properties such as improved stability …

Chalcones enable the biosynthesis of flavonoids which protect plants from infections and
parasites and have emerged as valuable medicines against diverse human diseases. The …

Benzothiophenes, activated by oxidation to the corresponding S‐oxides, undergo C− H/C−
H‐type coupling with phenols to give C4 arylation products. While an electron‐withdrawing …

The reaction of cyclic nitronic esters (isoxazoline-and 5, 6-dihydro-4 H-1, 2-oxazine-N-
oxides) with hydrochloric acid affords geminal chloronitroso compounds bearing a distant …

The first catalytic asymmetric interrupted Attanasi reaction has been established. Under the
catalysis of a bifunctional organocatalyst, the condensation of cyclic β-keto esters with …

A palladium-catalyzed domino reaction of alkene-tethered oxime esters is reported. This
transformation uses an air-stable palladium precatalyst that initiates a Narasaka–Heck …

The Nazarov cyclization has been established as a powerful tool in constructing
cyclopentenone skeletons. In sharp contrast, oxa-Nazarov cyclization that affords …

The particular and unique mechanism of the copper‐catalyzed reaction between azides and
alkynes (CuAAC) has not only allowed for the efficient synthesis of 1, 2, 3‐trisubstituted 1, 4 …