Among the fundamental chemical transformations in organic synthesis, rearrangement has
been recognized as powerful and reliable reactions for the construction of carbon–carbon or …

The Piancatelli reaction, which is the rearrangement of 2-furylcarbinol to cyclopentenone,
involves a key furanoxonium ion intermediate and a furan ring opening-4π electrocyclization …

An enantioselective three-component rearrangement of alkenylfurans with various cycloalkyl
silyl peroxides and anilines has been developed by merging photoredox catalysis with chiral …

The first Lewis acid and chiral Brønsted acid cooperatively catalyzed asymmetric cascade
ring opening/aza-Piancatelli rearrangement reaction of furyl-substituted donor–acceptor …

As one of the most fundamental rearrangement reactions, the classical Piancatelli reaction
mainly relies on the use of α-furylcarbinols and is initiated by an acid-promoted …

The asymmetric synthesis of bridged tetrahydrobenzo [b] azepine and oxepine derivatives
through chiral Brønsted acid catalyzed asymmetric aza-Piancatelli rearrangement/Michael …

A chiral Brønsted acid catalyzed highly enantio-and diastereoselective cascade cyclization
has been developed to streamline the synthesis of valuable multifunctionalized …

The asymmetric three-component rearrangement of alkenylfurans with various sulfonyl
chlorides and anilines is developed via copper (I) and chiral vanadium cooperative …

A chiral N, N′-dioxide/cobalt (II) complex catalyzed highly diastereoselective and
enantioselective tandem aza-Piancatelli rearrangement/intramolecular Diels–Alder reaction …

The development of a stereoselective aza‐Piancatelli reaction to access 4‐
aminocyclopentenones is reported. This transformation relies on the use of chiral o‐sulfinyl …