From stable radicals to thermally robust high-spin diradicals and triradicals

C Shu, Z Yang, A Rajca - Chemical Reviews, 2023 - ACS Publications
Stable radicals and thermally robust high-spin di-and triradicals have emerged as important
organic materials due to their promising applications in diverse fields. New fundamental …

Molecular and Supramolecular Materials: From Light-Harvesting to Quantum Information Science and Technology

Y Zhang, CP Oberg, Y Hu, H Xu, M Yan… - The Journal of …, 2024 - ACS Publications
The past two decades have witnessed immense advances in quantum information
technology (QIT), benefited by advances in physics, chemistry, biology, and materials …

Molecular one‐and two‐qubit systems with very long coherence times

D Schäfter, J Wischnat, L Tesi, JA De Sousa… - Advanced …, 2023 - Wiley Online Library
General‐purpose quantum computation and quantum simulation require multi‐qubit
architectures with precisely defined, robust interqubit interactions, coupled with local …

Stabilizing Organic Radical Anion in Water by Metal–Organic Frameworks with Enhanced Stability for NIR Photothermal Antibacterial Therapy

Z Huang, Y Wang, Y Yang, Y Gao, Y Luo, X Li… - ACS Materials …, 2024 - ACS Publications
Tremendous efforts have been made in the development of highly stable organic radicals,
especially in water and at high temperatures. The development, as yet, is mainly restricted to …

Methyl-driven overhauser dynamic nuclear polarization

FA Perras, DF Flesariu, SA Southern… - The Journal of …, 2022 - ACS Publications
The Overhauser effect is unique among DNP mechanisms in that it requires the modulation
of the electron–nuclear hyperfine interactions. While it dominates DNP in liquids and metals …

Molecular Spin Qubits Impregnated in a Hexagonal Self-Ordered Mesoporous Silica

XF Jiang, ZB Hu, C Shao, Z Ouyang, Z Wang… - Chemistry of …, 2022 - ACS Publications
Quantum computing is one of the most important technologies in this century. As a class of
qubit material in quantum computing devices, molecule-based electron spin clusters have …

Thermally Ultrarobust S = 1/2 Tetrazolinyl Radicals: Synthesis, Electronic Structure, Magnetism, and Nanoneedle Assemblies on Silicon Surface

Z Yang, M Pink, EM Nowik-Boltyk, S Lu… - Journal of the …, 2023 - ACS Publications
Open-shell organic molecules, including S= 1/2 radicals, may provide enhanced properties
for several emerging technologies; however, relatively few synthesized to date possess …

Tunable Quantum Coherence of Luminescent Molecular Spins Organized via Block Copolymer Self‐Assembly

L Hou, YS Zhang, Y Zhang, SD Jiang… - Advanced Quantum …, 2024 - Wiley Online Library
Electronic or nuclear spins represent promising candidates of qubits for applications in
quantum information technologies and spintronic devices. However, it remains a challenge …

Blatter radical-decorated silica as a prospective adsorbent for selective NO capture from air

AS Poryvaev, E Gjuzi, AA Yazikova… - … applied materials & …, 2023 - ACS Publications
Nitrogen oxides are adverse poisonous gases present in the atmosphere and having
detrimental effects on the human health and environment. In this work, we propose a new …

Discs, dumbbells and superdiscs: Molecular and supermolecular architecture dependent magnetic behavior of mesogenic Blatter radical derivatives

S Kapuściński, J Szczytko, D Pociecha… - Materials Chemistry …, 2021 - pubs.rsc.org
A series of isomeric supermolecular bi-and tri-radicals, in which “half disc” mesogens are
connected 1, 4-and 1, 3, 5-through benzene, respectively, are investigated for liquid …