A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …

The variety of functionalities and porous structures inherent to metal-organic frameworks
(MOFs) together with the facile tunability of their properties makes these materials suitable …

Modulation of the local electronic structure and microenvironment of catalytic metal sites
plays a critical role in electrocatalysis, yet remains a grand challenge. Herein, PdCu …

Metal nanoclusters (NCs) with atomically precise structures have sparked interest in
catalysis. Unfortunately, their high aggregation tendency and the spatial resistance of …

High-entropy alloys (HEAs), which are defined as near-equimolar alloys of five or more
elements, are attracting ever increasing attention because of the unique properties in a …

While the microenvironment around catalytic sites is recognized to be crucial in
thermocatalysis, its roles in photocatalysis remain subtle. In this work, a series of sandwich …

Charge transfer between metal sites and supports is crucial for catalysis. Redox‐inert
supports are usually unfavorable due to their less electronic interaction with metal sites …

Metal–organic framework (MOF) nanoparticles, also called porous coordination polymers,
are a major part of nanomaterials science, and their role in catalysis is becoming central …

Metal–organic frameworks (MOFs) have emerged as one of the most widely investigated
materials in catalysis mainly due to their excellent component tunability, high surface area …

The exposed facets of supported catalysts play a crucial role in catalysis; however, they are
usually ignored and related studies remain rare. Herein, we have fabricated a series of …