Liquid electrolyte: The nexus of practical lithium metal batteries

H Wang, Z Yu, X Kong, SC Kim, DT Boyle, J Qin, Z Bao… - Joule, 2022 - cell.com
The specific energy of commercial lithium (Li)-ion batteries is reaching the theoretical limit.
Future consumer electronics and electric vehicle markets call for the development of high …

Fluorination in advanced battery design

Y Wang, Z Wu, FM Azad, Y Zhu, L Wang… - Nature Reviews …, 2024 - nature.com
The increasing demand for high-performance rechargeable batteries, particularly in energy
storage applications such as electric vehicles, has driven the development of advanced …

Calendar aging of silicon-containing batteries

JD McBrayer, MTF Rodrigues, MC Schulze… - Nature Energy, 2021 - nature.com
High-energy batteries for automotive applications require cells to endure well over a decade
of constant use, making their long-term stability paramount. This is particularly challenging …

Diverting exploration of silicon anode into practical way: a review focused on silicon-graphite composite for lithium ion batteries

P Li, H Kim, ST Myung, YK Sun - Energy Storage Materials, 2021 - Elsevier
With the increasing need for maximizing the energy density of energy storage devices,
silicon (Si) active material with ultrahigh theoretical capacity has been considered as …

Rapid determination of solid-state diffusion coefficients in Li-based batteries via intermittent current interruption method

YC Chien, H Liu, AS Menon, WR Brant… - Nature …, 2023 - nature.com
The galvanostatic intermittent titration technique (GITT) is considered the go-to method for
determining the Li+ diffusion coefficients in insertion electrode materials. However, GITT …

Fluorine-Free Lithium Metal Batteries with a Stable LiF-Free Solid Electrolyte Interphase

Z Jiang, C Li, T Yang, Y Deng, J Zou, Q Zhang… - ACS Energy …, 2024 - ACS Publications
Lithium fluoride (LiF), generated by the decomposition of fluoride in lithium metal batteries
(LMBs), is considered an essential component for stabilizing metallic Li. However, the …

Fluorine‐free electrolytes for lithium and sodium batteries

G Hernández, R Mogensen, R Younesi… - Batteries & …, 2022 - Wiley Online Library
Fluorinated components in the form of salts, solvents and/or additives are a staple of
electrolytes for high‐performance Li‐and Na‐ion batteries, but this comes at a cost. Issues …

Sodium borates: expanding the electrolyte selection for sodium‐ion batteries

DMC Ould, S Menkin, HE Smith… - Angewandte …, 2022 - Wiley Online Library
Sodium‐ion batteries (SIBs) are a promising grid‐level storage technology due to the
abundance and low cost of sodium. The development of new electrolytes for SIBs is …

A wide-temperature-range, low-cost, fluorine-free battery electrolyte based on sodium bis (oxalate) borate

R Mogensen, A Buckel, S Colbin… - Chemistry of …, 2021 - ACS Publications
Common battery electrolytes comprise organic carbonate solvents and fluorinated salts
based on hexafluorophosphate (PF6–) anions. However, these electrolytes suffer from high …

Initial SEI formation in LiBOB-, LiDFOB-and LiBF 4-containing PEO electrolytes

EKW Andersson, LT Wu, L Bertoli, YC Weng… - Journal of Materials …, 2024 - pubs.rsc.org
A limiting factor for solid polymer electrolyte (SPE)-based Li-batteries is the functionality of
the electrolyte decomposition layer that is spontaneously formed at the Li metal anode. A …