The surface and interface coordination structures of heterogeneous metal catalysts are
crucial to their catalytic performance. However, the complicated surface and interface …

N-Heterocyclic carbenes (NHCs) have become without doubt one of the most exciting and
popular species in chemical science due to the ease of their preparation and modularity in …

It is well-recognized that N-heterocyclic carbene (NHC) ligands have provided a new
dimension to the design of homogeneous catalysts. Part of the success of this type of ligands …

N-Heterocyclic carbenes (NHCs) have emerged as one of the most useful class of ligands
for metal complexes primarily due to their relatively easy synthesis, broad structural and …

Organotransition metal complexes capable of forming metalloradicals have been an
intriguing subject of study for the past fifty years. Of these, rhodium porphyrin complexes …

Porphyrin and their versatile metal complexes represent a special class of coordination
compounds possessing unique physical-chemical properties. The achievements in the …

New promising photoactive functionalized pyrazinoporphyrins were prepared and
preliminarily tested as homogeneous catalysts in the photooxidation of organic sulfides. An …

Porphyrins are conjugated, stable chromophores with a central core that binds a variety of
metal ions and an easily functionalized peripheral framework. By combining the catalytic …

Janus di-N-heterocyclic carbene (NHC) ligands are a subclass of poly-NHCs that feature
coordination to two transition metals in a facially opposed manner. The combination of the …

This review highlights the recent developments in the field of metalloporphyrins as optical
probes for biologically relevant molecules, such as nitric oxide (NO) and hydrogen sulfide …