Advances in the E → Z Isomerization of Alkenes Using Small Molecule Photocatalysts

T Nevesely, M Wienhold, JJ Molloy, R Gilmour - Chemical reviews, 2021 - ACS Publications
Geometrical E→ Z alkene isomerization is intimately entwined in the historical fabric of
organic photochemistry and is enjoying a renaissance (Roth et al. Angew. Chem., Int. Ed …

Advances in the chemistry of tetrahydroquinolines

V Sridharan, PA Suryavanshi, JC Menendez - Chemical reviews, 2011 - ACS Publications
1.1. General Heterocyclic compounds, especially nitrogen heterocycles, are the most
important class of compounds in the pharmaceutical and agrochemical industries, with …

[HTML][HTML] A 13-million turnover-number anionic Ir-catalyst for a selective industrial route to chiral nicotine

C Yin, YF Jiang, F Huang, CQ Xu, Y Pan, S Gao… - Nature …, 2023 - nature.com
Developing catalysts with both useful enantioselectivities and million turnover numbers
(TONs) for asymmetric hydrogenation of ketones is attractive for industrial production of high …

Catalytic homogeneous asymmetric hydrogenation: successes and opportunities

CSG Seo, RH Morris - Organometallics, 2018 - ACS Publications
This is an overview of successes in the realm of catalytic homogeneous asymmetric
hydrogenation of substrates primarily of interest in the synthesis of pharmaceuticals in order …

Asymmetric hydrogenation of olefins using chiral crabtree-type catalysts: scope and limitations

JJ Verendel, O Pamies, M Dieguez… - Chemical …, 2014 - ACS Publications
The asymmetric hydrogenation of alkenes using transition metal catalysts continues to be a
growing field and a fundamental tool for organic synthetic chemists. In contrast to, for …

Catalytic asymmetric hydroamination of unactivated internal olefins to aliphatic amines

Y Yang, SL Shi, D Niu, P Liu, SL Buchwald - Science, 2015 - science.org
Catalytic assembly of enantiopure aliphatic amines from abundant and readily available
precursors has long been recognized as a paramount challenge in synthetic chemistry …

Amine (imine) diphosphine iron catalysts for asymmetric transfer hydrogenation of ketones and imines

W Zuo, AJ Lough, YF Li, RH Morris - Science, 2013 - science.org
A rational approach is needed to design hydrogenation catalysts that make use of Earth-
abundant elements to replace the rare elements such as ruthenium, rhodium, and palladium …

Developing ligands for palladium (II)-catalyzed C–H functionalization: intimate dialogue between ligand and substrate

KM Engle, JQ Yu - The Journal of organic chemistry, 2013 - ACS Publications
Homogeneous transition-metal-catalyzed reactions are indispensable to all facets of modern
chemical synthesis. It is thus difficult to imagine that for much of the early 20th century, the …

The growing impact of catalysis in the pharmaceutical industry

CA Busacca, DR Fandrick, JJ Song… - Advanced Synthesis …, 2011 - Wiley Online Library
Catalysis has become increasingly important for the pharmaceutical industry. Catalysis is a
critical technology that enables economical and environmentally‐sound manufacturing …

P, N ligands in asymmetric catalysis

MP Carroll, PJ Guiry - Chemical Society Reviews, 2014 - pubs.rsc.org
P, N ligands are an important class of ligands for asymmetric catalysis. In this tutorial review
an up to date account of recent applications of these ligands in asymmetric catalysis is …