Monoligated palladium (0) species, L1Pd (0), have emerged as the most active catalytic
species in the cross-coupling cycle. Today, there are methods available to generate the …

Palladium catalysed cross-couplings reactions have been a dominant method in synthetic
chemistry for decades. Despite this, the role of the solvent is often taken for granted and …

Suzuki–Miyaura (SM) cross-coupling is arguably the most widely-applied transition metal
catalysed carbon–carbon bond forming reaction to date. Its success originates from a …

A 'principles and practice'tutorial-style review of the application of solution-phase NMR in the
analysis of the mechanisms of homogeneous organic and organometallic reactions and …

pH–rate profiles for aqueous–organic protodeboronation of 18 boronic acids, many widely
viewed as unstable, have been studied by NMR and DFT. Rates were pH-dependent, and …

" One impressive and compressive book.... This review would have to be book size to do full
justice to all the insights in this volume."—Journal of Metals Online Fully updated and …

A photoredox-catalyzed C–H functionalization of heteroarenes using a variety of primary,
secondary, and tertiary alkyltrifluoroborates is reported. Using Fukuzumi's …

Azine‐containing biaryls are ubiquitous scaffolds in many areas of chemistry, and efficient
methods for their synthesis are continually desired. Pyridine rings are prominent amongst …

Boronic acids which quickly deboronate under basic conditions, such as
polyfluorophenylboronic acid and five-membered 2-heteroaromatic boronic acids, are …

Abstract The Suzuki–Miyaura coupling is one of the few transition‐metal‐catalyzed C C
bond‐forming reactions that have been used in applications ranging from discovery …