Halogen Bonds of Halogen (I) Ions─ Where Are We and Where to Go?

LHE Wieske, M Erdelyi - Journal of the American Chemical …, 2023 - ACS Publications
Halenium ions, X+, are particularly strong halogen-bond donors that interact with two Lewis
bases simultaneously to form linear [D··· X··· D]+-type halonium complexes. Their three …

Halogen bonds of halonium ions

L Turunen, M Erdélyi - Chemical Society Reviews, 2020 - pubs.rsc.org
Due to their electron deficiency, halonium ions act as particularly strong halogen bond
donors. By accepting electrons in both lobes of their empty p-orbital, they are capable of …

Halogen bonding, chalcogen bonding, pnictogen bonding, tetrel bonding: Origins, current status and discussion

L Brammer - Faraday Discussions, 2017 - pubs.rsc.org
The role of the closing lecture in a Faraday Discussion is to summarise the contributions
made to the Discussion over the course of the meeting and in so doing capture the main …

Halogen‐Bonded Organic Framework (XOF) Based on Iodonium‐Bridged N⋅⋅⋅I+⋅⋅⋅N Interactions: A Type of Diphase Periodic Organic Network

G Gong, S Lv, J Han, F Xie, Q Li, N Xia… - Angewandte …, 2021 - Wiley Online Library
Due to the fascinating structures and wide applications, porous materials with open
frameworks have attracted more and more attentions. Herein, a novel two‐dimensional (2D) …

The halogen bond: Nature and applications

PJ Costa - Physical Sciences Reviews, 2017 - degruyter.com
The halogen bond, corresponding to an attractive interaction between an electrophilic
region in a halogen (X) and a nucleophile (B) yielding a R− X⋯ B contact, found applications …

The interplay between hydrogen and halogen bonding: substituent effects and their role in the hydrogen bond enhanced halogen bond

J Sun, DA Decato, VS Bryantsev, EA John… - Chemical …, 2023 - pubs.rsc.org
The hydrogen bond enhanced halogen bond (HBeXB) has recently been used to effectively
improve anion binding, organocatalysis, and protein structure/function. In this study, we …

Halogen and Hydrogen Bonding between (N‐Halogeno)‐succinimides and Pyridine Derivatives in Solution, the Solid State and In Silico

V Stilinović, G Horvat, T Hrenar… - … –A European Journal, 2017 - Wiley Online Library
A study of strong halogen bonding within three series of halogen‐bonded complexes,
derived from seven para‐substituted pyridine derivatives and three N‐halosuccinimides …

Carbonyl hypoiodites as extremely strong halogen bond donors

S Yu, JS Ward, KN Truong, K Rissanen - Angewandte Chemie, 2021 - Wiley Online Library
Neutral halogen‐bonded O− I− N complexes were prepared from in situ formed carbonyl
hypoiodites and aromatic organic bases. The carbonyl hypoiodites have a strongly polarized …

Strong N−X⋅⋅⋅O−N Halogen Bonds: A Comprehensive Study on N‐Halosaccharin Pyridine N‐Oxide Complexes

R Puttreddy, JM Rautiainen, T Mäkelä… - Angewandte Chemie …, 2019 - Wiley Online Library
A study of the strong N− X⋅⋅⋅− O− N+ (X= I, Br) halogen bonding interactions reports 2× 27
donor× acceptor complexes of N‐halosaccharins and pyridine N‐oxides (PyNO). DFT …

Nano-sized I12L6 molecular capsules based on the [N⋅⋅⋅ I+⋅⋅⋅ N] halogen bond

L Turunen, U Warzok, CA Schalley, K Rissanen - Chem, 2017 - cell.com
Self-assembly of pre-organized subunits with a concave overall shape is an effective
strategy for the synthesis of supramolecular capsules. We report the synthesis of a cavitand …