Aminocarbyne ligands in organometallic chemistry

L Biancalana, F Marchetti - Coordination Chemistry Reviews, 2021 - Elsevier
Following the former synthetic work on group 6 metal complexes, aminocarbyne
(aminoalkylidyne) ligands have become popular across various transition metal groups …

Constructing organometallic architectures from aminoalkylidyne diiron complexes

F Marchetti - European Journal of Inorganic Chemistry, 2018 - Wiley Online Library
The chemistry of diiron complexes has seen a recent renaissance, due to the prominent role
played by the element iron in the development of sustainable synthetic processes and the …

The choice of μ-vinyliminium ligand substituents is key to optimize the antiproliferative activity of related diiron complexes

B Campanella, S Braccini, G Bresciani… - Metallomics, 2023 - academic.oup.com
Diiron vinyliminium complexes constitute a large family of organometallics displaying a
promising anticancer potential. The complexes [Fe2Cp2 (CO)(μ-CO){μ-η1: η3-C (R3) C (R4) …

N-Indolyl diiron vinyliminium complexes exhibit antiproliferative effects in cancer cells associated with disruption of mitochondrial homeostasis, ROS scavenging, and …

G Bresciani, J Cervinka, H Kostrhunova… - Chemico-Biological …, 2023 - Elsevier
The indole scaffold has been established as a key organic moiety for developing new drugs;
on the other hand, a range of diiron bis-cyclopentadienyl complexes have recently emerged …

Anticancer potential of diiron vinyliminium complexes

D Rocco, LK Batchelor, G Agonigi… - … A European Journal, 2019 - Wiley Online Library
Although ferrocene derivatives have attracted considerable attention as possible anticancer
agents, the medicinal potential of diiron complexes has remained largely unexplored …

Anticancer diiron vinyliminium complexes: a structure–activity relationship study

S Braccini, G Rizzi, L Biancalana, A Pratesi, S Zacchini… - Pharmaceutics, 2021 - mdpi.com
A series of 16 novel diiron complexes of general formula [Fe2Cp2 (CO)(μ-CO){μ-η1: η3-C
(R′) C (R ″) CN (R)(Y)}] CF3SO3 (2–7), bearing different substituents on the bridging …

C C Bond Formation in Diiron Complexes

R Mazzoni, M Salmi, V Zanotti - Chemistry–A European …, 2012 - Wiley Online Library
The growing effort to design new sustainable synthetic methodologies, based on readily
available and environmentally friendly transition metals, has boosted research on iron …

Diiron complexes bearing bridging hydrocarbyl ligands as electrocatalysts for proton reduction

R Mazzoni, A Gabiccini, C Cesari, V Zanotti… - …, 2015 - ACS Publications
Diiron complexes with bridging hydrocarbyl ligands and containing CO and Cp ligands (Cp=
η5-C5H5) have been investigated as possible electrocatalysts for H2 production. In …

DFT Mechanistic Insights into the Alkyne Insertion Reaction Affording Diiron μ-Vinyliminium Complexes and New Functionalization Pathways

G Ciancaleoni, S Zacchini, V Zanotti… - Organometallics, 2018 - ACS Publications
Insertion of propyne or 2-butyne into the Fe–carbyne bond belonging to the fragment
[Fe2Cp2 (CO)(μ-CO){μ-CNMe (R)}]+(R= Me or Xyl= 2, 6-C6H3Me2) was investigated via …

Antiproliferative and bactericidal activity of diiron and monoiron cyclopentadienyl carbonyl complexes comprising a vinyl‐aminoalkylidene unit

D Rocco, N Busto, C Pérez‐Arnaiz… - Applied …, 2020 - Wiley Online Library
A series of diiron complexes with two cyclopentadienyls, two carbonyls, and one bridging
vinyl‐aminoalkylidene as ligands,[3a–h] CF3SO3 and [4a–d] CF3SO3, was synthesized in …