Synergistic dual transition metal catalysis

UB Kim, DJ Jung, HJ Jeon, K Rathwell… - Chemical Reviews, 2020 - ACS Publications
Synergistic catalysis, a type of plural catalysis which utilizes at least two different catalysts to
enable a reaction between two separately activated substrates, has unlocked a plethora of …

Direct decarboxylative Giese reactions

DM Kitcatt, S Nicolle, AL Lee - Chemical Society Reviews, 2022 - pubs.rsc.org
The quest to find milder and more sustainable methods to generate highly reactive, carbon-
centred intermediates has led to a resurgence of interest in radical chemistry. In particular …

Metal-catalysed C–Het (F, O, S, N) and C–C bond arylation

B Zhao, T Rogge, L Ackermann, Z Shi - Chemical Society Reviews, 2021 - pubs.rsc.org
The formation of C–aryl bonds has been the focus of intensive research over the last
decades for the construction of complex molecules from simple, readily available feedstocks …

Cross-coupling of aromatic esters and amides

R Takise, K Muto, J Yamaguchi - Chemical Society Reviews, 2017 - pubs.rsc.org
Catalytic cross-coupling reactions of aromatic esters and amides have recently gained
considerable attention from synthetic chemists as de novo and efficient synthetic methods to …

Visible‐light‐induced decarboxylative functionalization of carboxylic acids and their derivatives

J Xuan, ZG Zhang, WJ Xiao - … Chemie International Edition, 2015 - Wiley Online Library
Visible‐light‐induced radical decarboxylative functionalization of carboxylic acids and their
derivatives has recently received considerable attention as a novel and efficient method to …

Decarboxylative reactions with and without light–a comparison

J Schwarz, B König - Green Chemistry, 2018 - pubs.rsc.org
Carboxylic acids have gained more and more importance as versatile and renewable
starting materials for the formation of platform molecules or high-value chemicals. Many …

Multimetallic-catalyzed C–C bond-forming reactions: from serendipity to strategy

LKG Ackerman-Biegasiewicz… - Journal of the …, 2023 - ACS Publications
The use of two or more metal catalysts in a reaction is a powerful synthetic strategy to access
complex targets efficiently and selectively from simple starting materials. While capable of …

Decarboxylation as the key step in C− C bond‐forming reactions

T Patra, D Maiti - Chemistry–A European Journal, 2017 - Wiley Online Library
C− C bond forming reactions incarnate the core of organic synthesis because of their
fundamental applications to molecular diversity and complexity. In recent years, use of …

Direct C− H transformation via iron catalysis

CL Sun, BJ Li, ZJ Shi - Chemical Reviews, 2011 - ACS Publications
The development and application of efficient, convenient, selective, and environmentally
benign synthetic methods is highly desirable in organic chemistry. With this requirement …

Acyl radical chemistry via visible-light photoredox catalysis

A Banerjee, Z Lei, MY Ngai - Synthesis, 2019 - thieme-connect.com
Visible-light photoredox catalysis enables easy access to acyl radicals under mild reaction
conditions. Reactive acyl radicals, generated from various acyl precursors such as …