Simulating coherent multidimensional spectroscopy of nonadiabatic molecular processes: From the infrared to the x-ray regime
Crossings of electronic potential energy surfaces in nuclear configuration space, known as
conical intersections, determine the rates and outcomes of a large class of photochemical …
conical intersections, determine the rates and outcomes of a large class of photochemical …
Recent advances in multidimensional ultrafast spectroscopy
TAA Oliver - Royal Society open science, 2018 - royalsocietypublishing.org
Multidimensional ultrafast spectroscopies are one of the premier tools to investigate
condensed phase dynamics of biological, chemical and functional nanomaterial systems. As …
condensed phase dynamics of biological, chemical and functional nanomaterial systems. As …
Vibronic mixing enables ultrafast energy flow in light-harvesting complex II
Since the discovery of quantum beats in the two-dimensional electronic spectra of
photosynthetic pigment-protein complexes over a decade ago, the origin and mechanistic …
photosynthetic pigment-protein complexes over a decade ago, the origin and mechanistic …
Conical intersections at interfaces revealed by phase-cycling interface-specific two-dimensional electronic spectroscopy (i2D-ES)
ZC Huang-Fu, NV Tkachenko, Y Qian… - Journal of the …, 2024 - ACS Publications
Conical intersections (CIs) hold significant stake in manipulating and controlling
photochemical reaction pathways of molecules at interfaces and surfaces by affecting …
photochemical reaction pathways of molecules at interfaces and surfaces by affecting …
Directing the path of light-induced electron transfer at a molecular fork using vibrational excitation
Ultrafast electron transfer in condensed-phase molecular systems is often strongly coupled
to intramolecular vibrations that can promote, suppress and direct electronic processes …
to intramolecular vibrations that can promote, suppress and direct electronic processes …
Time-resolved photoelectron spectroscopy of conical intersections with attosecond pulse trains
D Jadoun, M Kowalewski - The Journal of Physical Chemistry …, 2021 - ACS Publications
Conical Intersections (CIs), which are believed to be ubiquitous in molecular and biological
systems, open up ultrafast nonradiative decay channels. A superposition of electronic states …
systems, open up ultrafast nonradiative decay channels. A superposition of electronic states …
The study of reactive intermediates in condensed phases
BK Carpenter, JN Harvey… - Journal of the American …, 2016 - ACS Publications
Novel experimental techniques and computational methods have provided new insight into
the behavior of reactive intermediates in solution. The results of these studies show that …
the behavior of reactive intermediates in solution. The results of these studies show that …
[HTML][HTML] Two-dimensional electronic–vibrational spectroscopy: Exploring the interplay of electrons and nuclei in excited state molecular dynamics
Two-dimensional electronic–vibrational spectroscopy (2DEVS) is an emerging
spectroscopic technique which exploits two different frequency ranges for the excitation …
spectroscopic technique which exploits two different frequency ranges for the excitation …
Experimental detection of branching at a conical intersection in a highly fluorescent molecule
Conical intersections are molecular configurations at which adiabatic potential-energy
surfaces touch. They are predicted to be ubiquitous, yet condensed-phase experiments …
surfaces touch. They are predicted to be ubiquitous, yet condensed-phase experiments …
Solvent mediated excited state proton transfer in Indigo Carmine
Excited state proton transfer (ESPT) is thought to be responsible for the photostability of
biological molecules, including DNA and proteins, and natural dyes such as indigo …
biological molecules, including DNA and proteins, and natural dyes such as indigo …