This review highlights key reactivities relying on C–C bond cleavages of cyclopropenes.
Metal-catalyzed and metal-free transformations are covered in reactions involving direct ring …

This short review focuses on the most relevant achievements in the field of cyclopropene
chemistry including their syntheses, reactivities, and applications. As the chemistry of …

While gold‐mediated synergistic catalytic processes involving transmetalations with other
metals are well understood, AuI/AuIII cycles in these reactions are rarely reported. Herein a …

An asymmetric multicomponent, interrupted Kinugasa allylic alkylation (IKAA) reaction has
been developed with a synergistic Cu‐catalyzed Kinugasa system and a Pd‐catalyzed …

Strained alkynes include arynes and cyclooctynes reacted with N-methoxyamides through
palladium-catalyzed C–H/N–H activation for the first time. A variety of important N …

A novel and efficient strategy for the synthesis of arylated furans was successfully developed
by a RhIII‐catalyzed coupling of N‐phenoxyacetamides and cyclopropenyl esters …

Cyclopropanes are unique three-member rings whose unusual bonding and inherent ring
strain make them valuable building blocks in modern organic synthesis. In this work, a Pd …

A novel tandem metal relay catalytic system was developed by combining gold-catalyzed
cycloisomerization with an early transition-metal-catalyzed inverse-electron-demand hetero …

A novel and efficient method for the synthesis of diversely functionalized furans is developed
via DBU-mediated tandem Michael addition/5-exo-dig-cycloisomerization of enynes and …

With the synergistic activation of alkynyl alcohols and alkynyl enones by a single gold
catalyst, diverse multisubstituted spirocyclopenta [c] furans were synthesized in good to …