Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

Organoborons have emerged as versatile building blocks in organic synthesis to achieve
molecular diversity and as carboxylic acid bioisosteres with broad applicability in drug …

Employing phenols and phenol derivatives as electrophiles for cross-coupling reactions has
numerous advantages over commonly used aryl halides in terms of environmental …

Regioselective functionalization of arenes remains a challenging problem in organic
synthesis. Steric interactions are often used to block sites adjacent to a given substituent, but …

The mechanochemical, solvent‐free, highly regioselective, rhodium‐catalyzed C− H
methylation of (hetero) arenes is reported. The reaction shows excellent functional‐group …

We report the catalytic reduction of a C–O bond and the borylation by a rhodium complex
bearing an X-type PAlP pincer ligand. We have revealed the reaction mechanism based on …

Organoboron and organosilane compounds are widely used in organic synthesis and
pharmaceuticals. In addition, the C–F bond functionalization is a useful tool for the …

Arylboron and arylphosphorus compounds represent privileged structural scaffolds in
synthetic chemistry for the construction of complex molecules. Transition-metal-mediated CB …

The first iron‐catalyzed defluorosilylation of unactivated gem‐difluoroalkenes was
developed, delivering gem‐disilylated alkenes and (E)‐silylated alkenes with excellent …