Applicability of the Delplot method for the determination of catalytic reaction sequences: Hydrodeoxygenation of γ-valerolactone on Ni2P/MCM-41

GN Yun, IT Ghampson, WJ Movick, V Vargheese… - Chemical Engineering …, 2020 - Elsevier
Contact-time measurements based on sites are used to investigate the reaction sequence of
the hydrodeoxygenation of γ-valerolactone (GVL) on Ni 2 P/MCM-41. The study is carried …

Joint kinetics: A new paradigm for chemical kinetics and chemical engineering

GS Yablonsky, D Constales, GB Marin - Current Opinion in Chemical …, 2020 - Elsevier
Joint kinetics, a new paradigm for chemical kinetics and chemical engineering, is proposed.
Its main idea is performing a battery of kinetic experiments from special initial compositions …

Chemical engineering kinetics of p-xylene chlorination in a gas-liquid agitated reactor

FP Rigas - Chemical Engineering Science, 2023 - Elsevier
This study aims at determining both the rate constants of chlorination of p-xylene with
molecular chlorine and FeCl 3 as a catalyst at 70° C and 90° C and the related chemical …

Quasi-invariants of chemical reactions in the ideal displacement reactor

NI Koltsov - Theoretical Foundations of Chemical Engineering, 2020 - Springer
Mathematical models of nonequilibrium processes in distributed systems are described by
partial differential equations with given boundary conditions and, as a rule, cannot be solved …

Invariant expressions for linear complex mechanisms: Generalization for polar two-step sub-mechanisms

D Branco, GS Yablonsky, GB Marin… - Chemical Engineering …, 2020 - Elsevier
We generalize the results on invariances found for linear two-step mechanism within our
approach to joint kinetics. It is demonstrated that similar invariances can be formulated for …

Rate constant ratios in the consecutive chlorination of liquid‐phase p‐xylene with Cl2 and antimony pentachloride as a catalyst

FP Rigas - International Journal of Chemical Kinetics, 2022 - Wiley Online Library
The rate constant ratios of the consecutive chlorination of p‐xylene at 70oC in a gas–liquid
semibatch reactor using molecular chlorine, dichloroethane as a solvent, and antimony …

Квазиинварианты химических реакций в реакторе идеального вытеснения

НИ Кольцов - Теоретические основы химической технологии, 2020 - elibrary.ru
Математические модели неравновесных процессов в распределенных системах
описываются дифференциальными уравнениями в частных производных с заданными …

[PDF][PDF] Joint kinetics: a new strategy in chemical kinetics

GS Yablonsky - 2019 - kxtp.kpi.ua
Since Guldberg-Waage's and Van't Hoff's times, the chemical equilibrium became one of the
favorite topics of physical chemistry and chemical engineering. Presently, the calculation of …