Organosulfur compounds have long played a vital role in organic chemistry and in the
development of novel chemical structures and architectures. Prominent among these …

Radical tri-and difluoromethylation (fluoromethylation) by photoredox catalysis has emerged
as a new synthetic methodology over the past several years. In particular, the strategy is …

A redox‐neutral intermolecular dicarbofunctionalization of styrenes with CO2 at atmospheric
pressure and carbon‐centered radicals is described. This mild protocol results in multiple …

It is well known that two-dimensional (2D) MXene-derived quantum dots (MQDs) inherit the
excellent physicochemical properties of the parental MXenes, as a Chinese proverb …

Recent advances in photoinduced trifluoromethylation and difluoroalkylation under
photocatalysis are summarized. Most of the photoredox reactions proceed efficiently under …

A novel visible-light-induced radical tandem trifluoromethylation/cyclization of unactivated
alkenes with sodium perfluoroalkanesulfinates (Rf= CF3, C3F7, C4F9, C6F13, C8F17) …

This review highlights the progress of aqueous fluoroalkylation over the past few decades.
Fluorine-containing functionalities are important design elements in new pharmaceuticals …

The difunctionalizative trifluoromethylation of unsaturated C− C bonds is a highly useful and
efficient method for the synthesis of trifluoromethyl compounds with attractive architectures …

A photoinduced, phosphoranyl radical-mediated protocol for the direct N–O cleavage of
strained cycloketone oximes via a polar/SET crossover process was developed for the first …

Styrenes represent a challenging class of substrates for current radical trifluoromethylation
and hydrotrifluoromethylation methods due to a myriad of potential side reactions. Herein …