Unravelling Irreversible Adsorbate Thermodynamics through Adsorption-Assisted Desorption

A Lawal, OA Abdelrahman - Langmuir, 2024 - ACS Publications
Strongly bound surface species like alkylamines adsorbed on the Brønsted acid site of
aluminosilicate zeolites exhibit negligible rates of molecular desorption, preventing them …

Kinetic Investigation on Solvating Alkylamine Hofmann Elimination over Brønsted Acidic Zeolites

H Chen, O Abdelrahman - 2024 - chemrxiv.org
The presence of solvents can significantly alter the reaction kinetics of catalytic conversions,
yet the mechanisms of the solvent effect remain widely debated and could greatly vary …