Technological insights on glycerol valorization into propanediol through thermocatalytic and synthetic biology approaches

A Yahyazadeh, A Bot, S Nanda, AK Dalai - Fermentation, 2023 - mdpi.com
The adverse effects of climate change, predominantly propelled by greenhouse gas
emissions from fossil fuels, underscore the urgency of seeking sustainable alternatives to …

Tuning the Selectivity of the Hydrogenation/Hydrogenolysis of 5‐Hydroxymethylfurfural under Batch Multiphase and Continuous‐Flow Conditions

D Rodríguez‐Padrón, A Perosa, L Longo… - …, 2022 - Wiley Online Library
The hydrogenation/hydrogenolysis of 5‐hydroxymethylfurfural (HMF) has been carried out
either under single (aqueous) phase or batch multiphase (MP) conditions using mutually …

CO 2-assisted hydrolytic hydrogenation of cellulose and cellulose-based waste into sorbitol over commercial Ru/C

D Polidoro, G Stamilla, M Feltracco, A Gambaro… - Green …, 2023 - pubs.rsc.org
A single-step protocol was developed for the hydrolytic hydrogenation of microcrystalline
cellulose into sorbitol over commercial carbon-supported Ru, in the presence of gaseous …

Recent progress on bimetallic catalysts for the production of fuels and chemicals from biomass and plastics by hydrodeoxygenation

L Liu, B Liu, Y Nakagawa, S Liu, L Wang… - Chinese Journal of …, 2024 - Elsevier
Valorization of biomass and plastics is an urgent assignment to achieve the goal of carbon
neutrality. Hydrodeoxygenation using bimetallic catalysts with distinct active sites is one of …

Chitin-derived nanocatalysts for reductive amination reactions

D Polidoro, D Rodriguez-Padron, A Perosa, R Luque… - Materials, 2023 - mdpi.com
Chitin, the second most abundant biopolymer in the planet after cellulose, represents a
renewable carbon and nitrogen source. A thrilling opportunity for the valorization of chitin is …

Multiphase Hydrogenation of d-Glucosamine Hydrochloride, N-Acetyl-d-Glucosamine, d-Glucose, and d-Maltose over Ru/C with Integrated Catalyst Recovery

D Polidoro, A Perosa, E Barbaro… - ACS Sustainable …, 2022 - ACS Publications
A multiphase (MP) system composed of two immiscible liquids, water and isooctane, and
commercial 5% Ru/C as a catalyst, both with and without an additional organic liquid (OL …

Microwave-assisted catalytic transfer hydrogenolysis of lignin-derived aromatic ethers over Ru/C

D Polidoro, M Selva, R Luque - Molecular Catalysis, 2023 - Elsevier
Cleavage of aromatic ether bonds through hydrogenolysis is one of the most promising
routes for depolymerisation and transformation of lignin into value-added chemicals. Herein …

High-Yield Synthesis of 1-Hydroxyhexane-2, 5-dione via Hydrogenation/Hydrolysis of 5-Hydroxymethyl-furfural in Ionic Liquid-Assisted Multi-Phase Systems

D Polidoro, IE Mihai, A Perosa… - … Sustainable Chemistry & …, 2023 - ACS Publications
Different multiphase (MP) systems comprising immiscible liquid water, a hydrocarbon, and
an ionic liquid (IL) were investigated for the combined hydrogenation/hydrolysis of 5 …

Isopropenyl Acetate for the Continuous-Flow Synthesis of Triacetin, Solketal Acetate, and Allyl Acetate from Pure or Crude Glycerol

D Rigo, D Polidoro, L Marcuzzo… - ACS Sustainable …, 2023 - ACS Publications
Isopropenyl acetate (iPAc) proved to be an effective green reagent for the chemical
upgrading of refined and crude glycerol (CG) into valuable products, such as allyl acetate …

Pure silica Beta zeolite supported copper species for efficient hydrogenolysis of glycerol to 1, 2-propanediol

J Huang, J Zhang, S Lu, Y Liang, FS Xiao - Biomass and Bioenergy, 2023 - Elsevier
Catalytic conversion of glycerol to 1, 2-propanediol is an important issue for sustainable
production of fine chemicals and biodiesel. Here it is found that pure silica Beta zeolite …