Given the critical importance of novel ligand development for transition-metal (TM) catalysis,
as well as the resurgence of the field of organosilicon chemistry and silyl ligands, to …

We report on an additive-free Mn (I)-catalyzed dehydrogenative silylation of terminal
alkenes. The most active precatalyst is the bench-stable alkyl bisphosphine Mn (I) complex …

An unprecedented quantum tunneling effect has been observed in catalytic Si− H bond
activations at room temperature. The cationic hydrido‐silyl‐iridium (III) complex,{Ir [SiMe (o …

Rh (III) complexes [Rh (H)(X)(κ2-NSi t Bu2OPy)(L)](X= Cl, L= PCy3, 2a; PH t Bu2, 2b; X= OTf,
L= PCy3, 3a; PH t Bu2, 3b)(NSi t Bu2OPy= 4-methylpyridin-2-yloxy-ditertbutylsilyl) have …

Unsaturated 14-electron Rh (III) complexes are of great interest because of their involvement
in stoichiometric and catalytic processes. Herein, we report the synthesis and …

Allylsilanes have long been recognized as key molecular building blocks in organic
synthesis that are routinely employed as nucleophilic allylating reagents. Although a great …

A new air-stable Si, S-chelating ligand has been developed and used in an iridium-
catalyzed ortho C–H borylation reaction with a broad substrate scope. This study provides …

The rhodium complex Rh (HL)(COD) Cl, 1, L being a functionalized N-heterocyclic carbene
(NHC) ligand with an oxygen-containing pendant arm, has been used as the entry point to …

Herein we report an experimental and computational study of a family of four coordinated 14-
electron complexes of Rh (III) devoid of agostic interactions. The complexes [X–Rh (κ3 (P, Si …

The selective synthesis of linear silanes from remote alkenes is reported. Four new silane‐
thioether bidentate proligands [SiMe2H (o‐C6H4SR)](R= iBu, pentyl, benzyl, neopentyl) …