[HTML][HTML] POP-type ligands: Variable coordination and hemilabile behaviour
GM Adams, AS Weller - Coordination Chemistry Reviews, 2018 - Elsevier
Hemilabile ligands–ligands containing two or more potential donors to a metal centre, of
which one or more can dissociate–have the ability to provide a transition metal complex with …
which one or more can dissociate–have the ability to provide a transition metal complex with …
Ruthenium (II)-diphosphine complexes containing acylthiourea ligands are effective against lung and breast cancers
GF Grawe, KM Oliveira, CM Leite, TD de Oliveira… - Dalton …, 2022 - pubs.rsc.org
We have synthesized and characterized three new ruthenium (II) diphosphine complexes
containing an acylthiourea ligand, with the general formula [Ru (DPEPhos)(O, S)(bipy)] PF6 …
containing an acylthiourea ligand, with the general formula [Ru (DPEPhos)(O, S)(bipy)] PF6 …
Intermolecular Alkene and Alkyne Hydroacylation with β‐S‐Substituted Aldehydes: Mechanistic Insight into the Role of a Hemilabile P–O–P Ligand
GL Moxham, H Randell‐Sly… - … A European Journal, 2008 - Wiley Online Library
A straightforward to assemble catalytic system for the intermolecular hydroacylation reaction
of β‐S‐substituted aldehydes with activated and unactivated alkenes and alkynes is …
of β‐S‐substituted aldehydes with activated and unactivated alkenes and alkynes is …
Ru (II)-Catalyzed N-Methylation of Amines Using Methanol as the C1 Source
C Gao, Y Li, M Wang, D Gong, L Zhao - ACS omega, 2023 - ACS Publications
Four ruthenium complexes were used as catalysts for the N-methylation of amines using
methanol as the C1 source under weak base conditions. The (DPEPhos) RuCl2PPh3 (1a) …
methanol as the C1 source under weak base conditions. The (DPEPhos) RuCl2PPh3 (1a) …
POP–Pincer Ruthenium Complexes: d6 Counterparts of Osmium d4 Species
J Alos, T Bolaño, MA Esteruelas, M Oliván… - Inorganic …, 2014 - ACS Publications
A wide range of ruthenium complexes stabilized by the POP–pincer ligand xant (P i Pr2) 2
(9, 9-dimethyl-4, 5-bis (diisopropylphosphino) xanthene) were prepared starting from cis …
(9, 9-dimethyl-4, 5-bis (diisopropylphosphino) xanthene) were prepared starting from cis …
Sterically Demanding Phosphines with 2,6-Dibenzhydryl-4-methylphenyl Core: Synthesis of RuII, PdII, and PtII Complexes, and Structural and Catalytic Studies
MK Pandey, JT Mague, MS Balakrishna - Inorganic Chemistry, 2018 - ACS Publications
The synthesis of sterically demanding aminophosphine and phosphinite ligands Ar*
NHPPh2 (1) and Ar* OPPh2 (2), based on 2, 6-dibenzhydryl-4-methylphenyl core having …
NHPPh2 (1) and Ar* OPPh2 (2), based on 2, 6-dibenzhydryl-4-methylphenyl core having …
An inexpensive and highly stable ligand 1, 4-bis (2-hydroxy-3, 5-di-tert-butylbenzyl) piperazine for Mizoroki–Heck and room temperature Suzuki–Miyaura cross …
S Mohanty, D Suresh, MS Balakrishna, JT Mague - Tetrahedron, 2008 - Elsevier
A bulky, inexpensive and simple bidentate ligand 1, 4-bis (2-hydroxy-3, 5-di-tert-butylbenzyl)
piperazine (1) has been synthesized and characterized. The palladium catalyst was formed …
piperazine (1) has been synthesized and characterized. The palladium catalyst was formed …
Selective C–Cl bond oxidative addition of chloroarenes to a POP–rhodium complex
SG Curto, MA Esteruelas, M Oliván, E Oñate… - …, 2017 - ACS Publications
The C–Cl bond cis oxidative addition of 12 chloroarenes, including chlorobenzene,
chlorotoluenes, chlorofluorobenzenes, and di-and trichlorobenzenes to RhH {xant (PiPr2) …
chlorotoluenes, chlorofluorobenzenes, and di-and trichlorobenzenes to RhH {xant (PiPr2) …
Thioether-Functionalized Ferrocenyl-bis(phosphonite), Fe{(C5H4)P(−OC10H6(μ-S)C10H6O−)}2: Synthesis, Coordination Behavior, and Application in Suzuki …
B Punji, JT Mague, MS Balakrishna - Inorganic chemistry, 2007 - ACS Publications
The thioether-functionalized metalloligand ferrocenyl-bis (phosphonite), Fe (C5H4PR) 2 (4,
R=− OC10H6 (μ-S) C10H6O−) is synthesized in three steps starting from ferrocene, and its …
R=− OC10H6 (μ-S) C10H6O−) is synthesized in three steps starting from ferrocene, and its …
Iridium-Promoted B–B Bond Activation: Preparation and X-ray Diffraction Analysis of a mer-Tris(boryl) Complex
MA Esteruelas, I Fernández, A Martínez… - Inorganic …, 2019 - ACS Publications
The tris (boryl) complex Ir (Bcat) 3 {κ3-P, O, P-[xant (PiPr2) 2]}[Bcat= catecholboryl; xant
(PiPr2) 2= 9, 9-dimethyl-4, 5-bis (diisopropylphosphino) xanthene] has been prepared and …
(PiPr2) 2= 9, 9-dimethyl-4, 5-bis (diisopropylphosphino) xanthene] has been prepared and …