Mechanical properties and peculiarities of molecular crystals

WM Awad, DW Davies, D Kitagawa… - Chemical Society …, 2023 - pubs.rsc.org
In the last century, molecular crystals functioned predominantly as a means for determining
the molecular structures via X-ray diffraction, albeit as the century came to a close the …

Martensitic transition in molecular crystals for dynamic functional materials

SK Park, Y Diao - Chemical Society Reviews, 2020 - pubs.rsc.org
Molecular martensitic materials are an emerging class of smart materials with enormous
tunability in physicochemical properties, attributed to the tailored molecular and crystal …

The rise of the dynamic crystals

P Naumov, DP Karothu, E Ahmed… - Journal of the …, 2020 - ACS Publications
The anticipated shift in the focal point of interest of solid-state chemists, crystal engineers,
and crystallographers from structure to properties to function parallels the need to apply our …

Autonomous self-healing organic crystals for nonlinear optics

S Mondal, P Tanari, S Roy, S Bhunia… - Nature …, 2023 - nature.com
Non-centrosymmetric molecular crystals have a plethora of applications, such as
piezoelectric transducers, energy storage and nonlinear optical materials owing to their …

Engineering photomechanical molecular crystals to achieve extraordinary expansion based on solid-state [2+ 2] photocycloaddition

TY Xu, F Tong, H Xu, MQ Wang, H Tian… - Journal of the American …, 2022 - ACS Publications
Photomechanical molecular crystals are promising candidates for photoactuators and can
potentially be implemented as smart materials in various fields. Here, we synthesized a new …

Organic radical ferroelectric crystals with martensitic phase transition

N Zhang, W Sun, Y Zhang, HH Jiang, RG Xiong… - Nature …, 2023 - nature.com
Organic martensitic compounds are an emerging type of smart material with intriguing
physical properties including thermosalient effect, ferroelasticity, and shape memory effect …

Manipulating light‐induced dynamic macro‐movement and static photonic properties within 1D isostructural hydrogen‐bonded molecular cocrystals

S Li, B Lu, X Fang, D Yan - Angewandte Chemie International …, 2020 - Wiley Online Library
Smart molecular crystals with light‐driven mechanical responses have received interest
owing to their potential uses in molecular machines, artificial muscles, and biomimetics …

Near-room-temperature martensitic actuation profited from one-dimensional hybrid perovskite structure

BD Liang, CC Fan, CD Liu, CY Chai, XB Han… - Nature …, 2022 - nature.com
Martensitic transformation, usually accompanied by ferroelastic and thermoelastic
behaviors, is an interesting and useful mechanical-related property upon external stimuli …

Relationship between spatially heterogeneous reaction dynamics and photochemical kinetics in single crystals of anthracene derivatives

S Kataoka, D Kitagawa, H Sotome, S Ito… - Chemical …, 2024 - pubs.rsc.org
Understanding physicochemical property changes based on reaction kinetics is required to
design materials exhibiting desired functions at arbitrary timings. In this work, we …

Reversible thermosalience in a one-dimensional coordination polymer preceded by anisotropic thermal expansion and the shape memory effect

BB Rath, G Gallo, RE Dinnebier… - Journal of the American …, 2021 - ACS Publications
Thermally responsive crystals hold great potential for their use as actuating materials by
acting as energy transducers to convert heat energy to mechanical work. Control over …