Polymers without petrochemicals: sustainable routes to conventional monomers

G Hayes, M Laurel, D MacKinnon, T Zhao… - Chemical …, 2022 - ACS Publications
Access to a wide range of plastic materials has been rationalized by the increased demand
from growing populations and the development of high-throughput production systems …

Toward green atom transfer radical polymerization: current status and future challenges

S Dworakowska, F Lorandi, A Gorczyński… - Advanced …, 2022 - Wiley Online Library
Reversible‐deactivation radical polymerizations (RDRPs) have revolutionized synthetic
polymer chemistry. Nowadays, RDRPs facilitate design and preparation of materials with …

Chemically recyclable polymers: a circular economy approach to sustainability

M Hong, EYX Chen - Green Chemistry, 2017 - pubs.rsc.org
The current practices in the generation and disposal of synthetic polymers are largely
unsustainable. As part of the solution, the development of biodegradable polymers, which …

Macromolecular engineering by atom transfer radical polymerization

K Matyjaszewski, NV Tsarevsky - Journal of the American …, 2014 - ACS Publications
This Perspective presents recent advances in macromolecular engineering enabled by
ATRP. They include the fundamental mechanistic and synthetic features of ATRP with …

Atom transfer radical polymerization (ATRP): current status and future perspectives

K Matyjaszewski - Macromolecules, 2012 - ACS Publications
Current status and future perspectives in atom transfer radical polymerization (ATRP) are
presented. Special emphasis is placed on mechanistic understanding of ATRP, recent …

Aliphatic polyester block polymers: renewable, degradable, and sustainable

MA Hillmyer, WB Tolman - Accounts of chemical research, 2014 - ACS Publications
Conspectus Nearly all polymers are derived from nonrenewable fossil resources, and their
disposal at their end of use presents significant environmental problems. Nonetheless …

Self-healing of covalently cross-linked polymers by reshuffling thiuram disulfide moieties in air under visible light.

Y Amamoto, H Otsuka, A Takahara… - … (Deerfield Beach, Fla.), 2012 - europepmc.org
Self-healing of covalently cross-linked polymers under an ambient visible light in the bulk
state, in air, at room temperature using radical exchange of thiuram disulfide units is …

ATRP in the design of functional materials for biomedical applications

DJ Siegwart, JK Oh, K Matyjaszewski - Progress in polymer science, 2012 - Elsevier
Atom Transfer Radical Polymerization (ATRP) is an effective technique for the design and
preparation of multifunctional, nanostructured materials for a variety of applications in …

Synthesis of biodegradable polymers from renewable resources

MJL Tschan, E Brulé, P Haquette, CM Thomas - Polymer Chemistry, 2012 - pubs.rsc.org
The vast majority of commodity materials are obtained from fossil fuels. However, many
studies predict that all fossil resources will be depleted within a few centuries. Biomass …

Synthesis and polymerization of bio-based acrylates: a review

C Veith, F Diot-Néant, SA Miller, F Allais - Polymer Chemistry, 2020 - pubs.rsc.org
Acrylates and polyacrylates have been produced massively due to their interesting
applications like Plexiglas. However, the contemporary issues of fossil depletion associated …