Breakdown of the Mott-Hubbard State in : A First-Order Insulator-Metal Transition with Collapse of Magnetism at 50 GPa

MP Pasternak, GK Rozenberg, GY Machavariani… - Physical Review Letters, 1999 - APS
Electronic and structural properties of the high-pressure phase of Fe 2 O 3 were determined
by combining the methods of Mössbauer spectroscopy, x-ray diffraction, and electrical …

Electronic structure and magnetic properties of at high pressure

GR Hearne, MP Pasternak, RD Taylor, P Lacorre - Physical Review B, 1995 - APS
The electronic ground state and magnetic properties of the wide-gapped antiferromagnetic
insulator LaFeO 3 have been investigated by Fe 57 Mössbauer spectroscopy at pressures …

Nature of the Verwey transition in magnetite () to pressures of 16 GPa

GK Rozenberg, GR Hearne, MP Pasternak, PA Metcalf… - Physical Review B, 1996 - APS
The relative conductivity of Fe 3 O 4 single crystals very close to ideal stoichiometry has
been measured as a function of pressure up to P= 16 GPa and in the temperature range of …

Pressure-induced breakdown of a correlated system: The progressive collapse of the Mott-Hubbard state in

WM Xu, O Naaman, GK Rozenberg, MP Pasternak… - Physical Review B, 2001 - APS
Mössbauer spectroscopy, resistance, and synchrotron x-ray-diffraction (XRD) methods were
combined for detailed studies of the pressure-induced breakdown of the strongly correlated …

Pressure induced Fe2++ Ti4+→ Fe3++ Ti3+ intervalence charge transfer and the Fe3+/Fe2+ ratio in natural ilmenite (FeTiO3) minerals

T Seda, GR Hearne - Journal of Physics: Condensed Matter, 2004 - iopscience.iop.org
Abstract The Fe 3+/Fe 2+ ratioin natural ilmenite (FeTiO 3) samples shows rapid increase
under pressure from ambient up to GPa, as deduced from 57 Fe Mössbauer pressure …

Pressure-Induced Concurrent Transformation to an Amorphous and Crystalline Phase in Berlinite-Type

MP Pasternak, GK Rozenberg, AP Milner… - Physical review …, 1997 - APS
X-ray diffraction, Raman scattering, and Mössbauer spectroscopy provide a diverse
description of the high pressure behavior of berlinite-type FePO 4. At a pressure of 2.5 (5) …

Insights into phase transformations from Mössbauer spectroscopy

CA McCammon - Reviews in Mineralogy and …, 2000 - pubs.geoscienceworld.org
The Mössbauer effect is the recoilless absorption and emission of γ-rays by specific nuclei in
a solid (Mössbauer 1958a, 1958b), and provides a means of studying the local atomic …

Electrical transport, magnetism, and spin-state configurations of high-pressure phases of FeS

S Takele, GR Hearne - Physical Review B, 1999 - APS
Both the nature of the electrical transport and magnetism of high-pressure phases of FeS
have been elucidated in relation to the spin-state configuration of Fe. This has been …

Electronic, magnetic and structural properties of the RFeO3 antiferromagnetic-perovskites at very high pressures

MP Pasternak, WM Xu, GK Rozenberg… - MRS Online …, 2002 - cambridge.org
At ambient pressure the orthorhombic perovskites R-orthoferrites (R Ξ Lu, Eu, Y, Pr, and La)
exhibit very large optical gaps. These large-gap Mott insulators in which the 3d5 high-spin …

Collapse of the charge disproportionation and covalency-driven insulator-metal transition in under pressure

P Adler, U Schwarz, K Syassen, GK Rozenberg… - Physical Review B, 1999 - APS
The effect of pressure on electronic properties and crystal structure of Sr 3 Fe 2 O 7 was
studied up to 45 GPa. Experimental methods employed were 57 Fe Mössbauer …