Arynes are among the most active organic intermediates and have found numerous
applications in expeditious preparation of substituted arenes. In the past 20 years, chemists …

Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …

Organoboronates represent a cornerstone functional group in modern synthesis owing to
their unique reactivity and divergent synthetic capability. Copper catalysis has become one …

Organoboron compounds are valuable synthetic intermediates that find application in a
diverse variety of processes including both C–X and C–C bond-forming transformations …

Alkenylboranes have been vital reagents in modern synthetic organic chemistry, whose
carbon–boron bond is transformable into a carbon–carbon bond stereoretentively to give …

Organoboronic acids and their derivatives are useful reagents in carbon–carbon and carbon–
heteroatom bond formations. 1 In addition to having reasonable reactivities, organoboronic …

Multi (boronate) esters have been attracting increasing attention as versatile building blocks
for the succinct and precise synthesis of complex molecules. However, there are a limited …

Water is one of the most abundant molecules on earth. It is inexpensive, especially when
compared to organic solvents, nonflammable, and nontoxic, it has a large heat capacity, and …

The first Cu-catalyzed asymmetric borylative cyclization of cyclohexadienone-containing 1, 6-
enynes is achieved through a tandem process: selective β-borylation of propargylic ether …

The first copper-catalyzed formal carboboration of alkynes, in which a C–B bond and a C–C
bond are created in a single catalytic cycle, is presented. The reaction proceeds with high …