Toward intrinsic catalytic rates and selectivities of zeolites in the presence of limiting diffusion and deactivation

CW Hullfish, JZ Tan, HI Adawi, ML Sarazen - ACS Catalysis, 2023 - ACS Publications
The goal of atom-and energy-efficient production of fuels and chemicals from renewable (ie,
biomass) and closed-carbon (ie, CO2 and waste plastic) feedstocks requires effective …

Kinetics of propylene epoxidation over extracrystalline gold active sites on Au/TS-1 catalysts

JW Arvay, W Hong, C Li, WN Delgass, FH Ribeiro… - Acs …, 2022 - ACS Publications
To determine whether the catalytic roles of extracrystalline and intracrystalline gold
nanoparticles supported on titanosilicate-1 (TS-1) for direct propylene epoxidation are …

Nested Metal Catalysts: Metal Atoms and Clusters Stabilized by Confinement with Accessibility on Supports

BC Gates, A Katz, J Liu - Precision Chemistry, 2023 - ACS Publications
Supported catalysts that are important in technology prominently include atomically
dispersed metals and metal clusters. When the metals are noble, they are typically …

Optimization of MOFs-induced strategy for preparing anatase-free hierarchical TS-1 towards 1-hexene epoxidation: TPAOH dosage regulation, silanization and …

G An, H Gao, Y Luo, Y Ouyang, G Wang, S Liu… - Microporous and …, 2023 - Elsevier
Metal organic frameworks (MOFs)-induced synthetic strategy has been proven a convenient
and efficient way for preparing anatase-free hierarchical TS-1 zeolite in our previous study …

Synthesis of micro-mesoporous TS-1 zeolite and its green catalytic oxidation of p-diethylbenzene

Y Guo, J Li, L Zhao, Q Xu, Z Song, J Wang, M Han… - Molecular …, 2024 - Elsevier
The micro-mesoporous TS-1 catalyst was synthesized by directly introducing NaOH during
the synthesis of zeolite. As the first choice for many oxidation reactions, TS-1/H 2 O 2 …

[HTML][HTML] Review and perspectives on TS-1 catalyzed propylene epoxidation

J Yang, S Liu, Y Liu, L Zhou, H Wen, H Wei, R Shen… - Iscience, 2024 - ncbi.nlm.nih.gov
Summary Titanium silicate zeolite (TS-1) is widely used in the research on selective
oxidations of organic substrates by H 2 O 2. Compared with the chlorohydrin process and …

CuOx Nanopatches Positioned at Lewis Acidic Sites of TiO2 for Propylene Epoxidation Using Molecular Oxygen

Z Lv, L Kang, X Pan, Y Su, H Wang, L Li, XY Liu… - ACS …, 2024 - ACS Publications
Controlling the precise placement of active metals on supports is highly desirable yet
challenging, which governs both the reaction pathway and the ultimate outcomes of catalytic …

A Career in Catalysis: Enrique Iglesia

DG Barton, A Bhan, P Deshlahra, R Gounder… - ACS …, 2024 - ACS Publications
Enrique Iglesia is an internationally recognized leader in the field of heterogeneous
catalysis. His trademark approach places a premium on kinetic and mechanistic descriptions …

Kinetic insights into reaction pathways of acrolein formation in propylene epoxidation by H2 and O2 over Au/TS-1 catalyst

W Du, Z Zhang, J Wang, N Song, X Duan… - Chemical Engineering …, 2024 - Elsevier
Propylene epoxidation by H 2 and O 2 to propylene oxide (HOPO), as a novel method for PO
production, has attracted widespread attention due to its economic and environmental …

Fabrication of gold nanoparticles supported on hollow microsphere of nanosized TS-1 for the epoxidation of propylene with H2 and O2

L Hou, S Yan, L Liu, J Liu, G Xiong - Chemical Engineering Journal, 2024 - Elsevier
The TS-1 microsphere was facilely prepared via a direct spray drying of the mixture
containing the nanocrystal TS-1 and mother liquor. The calcined TS-1 zeolites possess a …