Knotting matters: orderly molecular entanglements

Z Ashbridge, SDP Fielden, DA Leigh, L Pirvu… - Chemical Society …, 2022 - pubs.rsc.org
Entangling strands in a well-ordered manner can produce useful effects, from shoelaces and
fishing nets to brown paper packages tied up with strings. At the nanoscale, non-crystalline …

Chirality in rotaxanes and catenanes

EMG Jamieson, F Modicom, SM Goldup - Chemical Society Reviews, 2018 - pubs.rsc.org
Although chiral mechanically interlocked molecules (MIMs) have been synthesised and
studied, enantiopure examples are relatively under-represented in the pantheon of reported …

Molecular knots

SDP Fielden, DA Leigh… - Angewandte Chemie …, 2017 - Wiley Online Library
The first synthetic molecular trefoil knot was prepared in the late 1980s. However, it is only in
the last few years that more complex small‐molecule knot topologies have been realized …

[HTML][HTML] Molecular weaving

ZH Zhang, BJ Andreassen, DP August, DA Leigh… - Nature Materials, 2022 - nature.com
Historically, the interlacing of strands at the molecular level has mainly been limited to
coordination polymers and DNA. Despite being proposed on a number of occasions, the …

Lanthanide-directed synthesis of luminescent self-assembly supramolecular structures and mechanically bonded systems from acyclic coordinating organic ligands

DE Barry, DF Caffrey, T Gunnlaugsson - Chemical Society Reviews, 2016 - pubs.rsc.org
Herein some examples of the use of lanthanide ions (f-metal ions) to direct the synthesis of
luminescent self-assembly systems (architectures) will be discussed. This area of lanthanide …

The rise and promise of molecular nanotopology

QH Guo, Y Jiao, Y Feng, JF Stoddart - CCS Chemistry, 2021 - chinesechemsoc.org
Molecular nanotopology—a term we coined recently—is a rapidly developing field of
research that is emerging out of the confluence of chemical topology with the mechanical …

[HTML][HTML] Metal ions in the synthesis of interlocked molecules and materials

JEM Lewis, PD Beer, SJ Loeb… - Chemical Society Reviews, 2017 - pubs.rsc.org
The use of metal ions to template the synthesis of catenanes by Sauvage and co-workers
was a pivotal moment in the development of the field of interlocked molecules. In this …

[HTML][HTML] A catenane that is topologically achiral despite being composed of oriented rings

N Pairault, F Rizzi, D Lozano, EMG Jamieson… - Nature Chemistry, 2023 - nature.com
Catenanes—molecules comprising two interlocking rings held together like links in a chain—
are topologically non-trivial: a catenane is a topological isomer of its separated rings, but the …

Ln‐MOF‐Based Hydrogel Films with Tunable Luminescence and Afterglow Behavior for Visual Detection of Ofloxacin and Anti‐Counterfeiting Applications

X Yu, AA Ryadun, DI Pavlov, TY Guselnikova… - Advanced …, 2024 - Wiley Online Library
Highly selective and sensitive quantitative detection of ofloxacin (OFX) at ultralow
concentrations in aqueous media and development of new afterglow materials remains a …

Circularly polarized luminescence of lanthanide complexes: From isolated individuals, discrete oligomers, to hierarchical assemblies

Y Zhong, Z Wu, Y Zhang, B Dong, X Bai - InfoMat, 2023 - Wiley Online Library
Circularly polarized luminescence (CPL) is the emission featured spatial orientation
equivalent to circular dichroism. Owning to the unique magnetic dipole‐allowed but electric …