Large easy-axis magnetic anisotropy in a series of trigonal prismatic mononuclear cobalt (II) complexes with zero-field hidden single-molecule magnet behaviour: the …
A Landart-Gereka, MM Quesada-Moreno… - Inorganic Chemistry …, 2022 - pubs.rsc.org
The complexes [Co (L)] X· S (X= CoCl42−, S= CH3CN (1); X= ZnCl42−, S= CH3OH (2)),[Co
(L)] X2· S (X= ClO4−, S= 2CH3OH (3) and X= BF4−(4)) and [Co (L)(NCS) 2](5), where L= the …
(L)] X2· S (X= ClO4−, S= 2CH3OH (3) and X= BF4−(4)) and [Co (L)(NCS) 2](5), where L= the …
A Pseudo‐Octahedral Cobalt (II) Complex with Bispyrazolylpyridine Ligands Acting as a Zero‐Field Single‐Molecule Magnet with Easy Axis Anisotropy
The homoleptic mononuclear compound [Co (bpp‐COOMe) 2](ClO4) 2 (1)(bpp‐COOMe=
methyl 2, 6‐di (pyrazol‐1‐yl) pyridine‐4‐carboxylate) crystallizes in the monoclinic C2/c …
methyl 2, 6‐di (pyrazol‐1‐yl) pyridine‐4‐carboxylate) crystallizes in the monoclinic C2/c …
Important role of intermolecular interaction in cobalt (II) single-ion magnet from single slow relaxation to double slow relaxation
ZB Hu, ZY Jing, MM Li, L Yin, YD Gao, F Yu… - Inorganic …, 2018 - ACS Publications
Two cobalt complexes with similar structures were synthesized using quinoline-2-carboxylic
acid (HL) as the ligand. Both complexes are six-coordinated in antitriangular prism …
acid (HL) as the ligand. Both complexes are six-coordinated in antitriangular prism …
Single-ion anisotropy and exchange coupling in cobalt (II)-radical complexes: insights from magnetic and ab initio studies
GK Gransbury, ME Boulon, RA Mole, RW Gable… - Chemical …, 2019 - pubs.rsc.org
The concurrent effects of single-ion anisotropy and exchange interactions on the electronic
structure and magnetization dynamics have been analyzed for a cobalt (II)-semiquinonate …
structure and magnetization dynamics have been analyzed for a cobalt (II)-semiquinonate …
Analysis of Magnetic Anisotropy and the Role of Magnetic Dilution in Triggering Single‐Molecule Magnet (SMM) Behavior in a Family of CoIIYIII Dinuclear …
MA Palacios, J Nehrkorn, EA Suturina… - … A European Journal, 2017 - Wiley Online Library
Three new closely related CoIIYIII complexes of general formula [Co (μ‐L)(μ‐X) Y (NO3)
2](X−= NO3− 1, benzoate 2, or 9‐anthracenecarboxylato 3) have been prepared with the …
2](X−= NO3− 1, benzoate 2, or 9‐anthracenecarboxylato 3) have been prepared with the …
Effect of noble metals on luminescence and single-molecule magnet behavior in the cyanido-bridged Ln–Ag and Ln–Au (Ln= Dy, Yb, Er) complexes
Self-assembly of lanthanide (III) complexes of 2, 2′: 6′, 2 ″-terpyridine (terpy) with
dicyanidoargentate (I) and dicyanidoaurate (I) anions in water results in the formation of six …
dicyanidoargentate (I) and dicyanidoaurate (I) anions in water results in the formation of six …
Evidence of field induced slow magnetic relaxation in cis-[Co (hfac) 2 (H 2 O) 2] exhibiting tri-axial anisotropy with a negative axial component
We report a combined experimental characterization and theoretical modeling of the hexa-
coordinated high-spin Co (II) complex cis-[Co (hfac) 2 (H2O) 2](I). The magnetic static field …
coordinated high-spin Co (II) complex cis-[Co (hfac) 2 (H2O) 2](I). The magnetic static field …
Modulating single-molecule magnetic behavior of a dinuclear erbium (III) complex by solvent exchange
[Er2 (thd) 4Pc]· 2C6H6 (1)(Hthd= 2, 2, 6, 6-tetramethylheptanedione), obtained as green
crystals from the reaction of [Er (thd) 3]· 2H2O with lithium phthalocyanine, Li2Pc, is a stable …
crystals from the reaction of [Er (thd) 3]· 2H2O with lithium phthalocyanine, Li2Pc, is a stable …
Confining single Er3+ ions in sub-3 nm NaYF4 nanoparticles to induce slow relaxation of the magnetisation
DA Gálico, EM Rodrigues, I Halimi, J Toivola… - Nature …, 2024 - nature.com
Molecular systems known as single-molecule magnets (SMMs) exhibit magnet-like
behaviour of slow relaxation of the magnetisation and magnetic hysteresis and have …
behaviour of slow relaxation of the magnetisation and magnetic hysteresis and have …
Toward steric control of guest binding modality: a cationic Co (II) complex exhibiting cation binding and zero-field relaxation
TJ Ozumerzifon, I Bhowmick, WC Spaller… - Chemical …, 2017 - pubs.rsc.org
We present the syntheses and characterization of several salts of a trigonal prismatic cobalt
(II) complex with a 1, 3, 5-triaminocyclohexane (tach)-derived ditopic ligand. The air-and …
(II) complex with a 1, 3, 5-triaminocyclohexane (tach)-derived ditopic ligand. The air-and …