[HTML][HTML] The transition metal-catalysed hydroboration reaction

SJ Geier, CM Vogels, JA Melanson… - Chemical Society …, 2022 - pubs.rsc.org
The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …

First-row d-block element-catalyzed carbon–boron bond formation and related processes

SK Bose, L Mao, L Kuehn, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Opportunities and challenges for catalysis in carbon dioxide utilization

MD Burkart, N Hazari, CL Tway, EL Zeitler - ACS Catalysis, 2019 - ACS Publications
The environmental and societal consequences of the increasing levels of carbon dioxide in
our atmosphere are among the most significant challenges society currently faces. Carbon …

[HTML][HTML] Catalysis using transition metal complexes featuring main group metal and metalloid compounds as supporting ligands

J Takaya - Chemical Science, 2021 - pubs.rsc.org
Recent development in catalytic application of transition metal complexes having an M–E
bond (E= main group metal or metalloid element), which is stabilized by a multidentate …

Recent progress in transition metal complexes supported by multidentate ligands featuring group 13 and 14 elements as coordinating atoms

T Komuro, Y Nakajima, J Takaya… - Coordination Chemistry …, 2022 - Elsevier
Over the past decade, significant progress has been made in the chemistry of transition
metal complexes supported by multidentate chelate ligands, such as pincer-type ligands, in …

Challenges and prospects in the catalytic conversion of carbon dioxide to formaldehyde

S Zhao, HQ Liang, XM Hu, S Li… - Angewandte …, 2022 - Wiley Online Library
Formaldehyde (HCHO) is a crucial C1 building block for daily‐life commodities in a wide
range of industrial processes. Industrial production of HCHO today is based on energy‐and …

[HTML][HTML] Emergence and applications of base metals (Fe, Co, and Ni) in hydroboration and hydrosilylation

SR Tamang, M Findlater - Molecules, 2019 - mdpi.com
Base metal catalysis offers an alternative to reactions, which were once dominated by
precious metals in hydrofunctionalization reactions. This review article details the …

[HTML][HTML] Manganese-catalyzed hydroboration of carbon dioxide and other challenging carbonyl groups

C Erken, A Kaithal, S Sen, T Weyhermüller… - Nature …, 2018 - nature.com
Reductive functionalization of the C= O unit in carboxylic acids, carbonic acid derivatives,
and ultimately in carbon dioxide itself is a challenging task of key importance for the …

(PSiP)Ni-Catalyzed (E)-Selective Semihydrogenation of Alkynes with Molecular Hydrogen

DJ Hale, MJ Ferguson, L Turculet - ACS Catalysis, 2021 - ACS Publications
The selective semihydrogenation of alkynes to (E)-alkenes is a challenging transformation
that is of significant synthetic interest. The development of direct hydrogenation catalysts for …

Selective Conversion of Carbon Dioxide to Formaldehyde via a Bis(silyl)acetal: Incorporation of Isotopically Labeled C1 Moieties Derived from Carbon Dioxide into …

M Rauch, Z Strater, G Parkin - Journal of the American Chemical …, 2019 - ACS Publications
The conversion of carbon dioxide to formaldehyde is a transformation that is of considerable
significance in view of the fact that formaldehyde is a widely used chemical, but this …