Nonplanar porphyrins: synthesis, properties, and unique functionalities
T Ishizuka, N Grover, CJ Kingsbury, H Kotani… - Chemical Society …, 2022 - pubs.rsc.org
Porphyrins are variously substituted tetrapyrrolic macrocycles, with wide-ranging biological
and chemical applications derived from metal chelation in the core and the 18π aromatic …
and chemical applications derived from metal chelation in the core and the 18π aromatic …
Trends in the usage of bidentate phosphines as ligands in nickel catalysis
AL Clevenger, RM Stolley, J Aderibigbe… - Chemical …, 2020 - ACS Publications
A critically important process in catalysis is the formation of an active catalyst from the
combination of a metal precursor and a ligand, as the efficacy of this reaction governs the …
combination of a metal precursor and a ligand, as the efficacy of this reaction governs the …
Room‐Temperature on‐spin‐switching and tuning in a porphyrin‐based multifunctional interface
HM Sturmeit, I Cojocariu, A Windischbacher… - Small, 2021 - Wiley Online Library
Molecular interfaces formed between metals and molecular compounds offer a great
potential as building blocks for future opto‐electronics and spintronics devices. Here, a …
potential as building blocks for future opto‐electronics and spintronics devices. Here, a …
Exploration of advanced porous organic polymers as a platform for biomimetic catalysis and molecular recognition
Nature has long been a dominant source of inspiration in the area of chemistry, serving as
prototypes for the design of materials with proficient performance. In this Feature article, we …
prototypes for the design of materials with proficient performance. In this Feature article, we …
[HTML][HTML] Computational study on the adsorption of small molecules to surface-supported Ni-porphyrins
A Windischbacher, P Puschnig - Inorganica Chimica Acta, 2023 - Elsevier
With their flexible oxidation and spin states, surface-supported metalloporphyrins are
attractive building blocks for tuneable, periodic spin interfaces. A technique to manipulate …
attractive building blocks for tuneable, periodic spin interfaces. A technique to manipulate …
[HTML][HTML] Extended π-conjugation: a key to magnetic anisotropy preservation in highly reactive porphyrins
I Cojocariu, S Carlotto, D Baranowski… - Journal of Materials …, 2023 - pubs.rsc.org
In this study, the magnetic anisotropy of metal complexes is explored for its crucial role in the
development of molecular materials for cutting-edge applications in spintronics, memory …
development of molecular materials for cutting-edge applications in spintronics, memory …
[HTML][HTML] Reversible redox reactions in metal-supported porphyrin: The role of spin and oxidation state
On-surface molecular functionalization paved the way for the stabilization of chelated ions in
different oxidation and spin states, allowing for the fine control of catalytic and magnetic …
different oxidation and spin states, allowing for the fine control of catalytic and magnetic …
[HTML][HTML] Distortion-driven spin switching in electron-doped metal porphyrins
I Cojocariu, S Carlotto, M Jugovac… - Journal of Materials …, 2022 - pubs.rsc.org
Electron injection into electrode-supported metal complexes allows for charge redistribution
within the molecule to be controlled. Here we show, for the first time, how the structural …
within the molecule to be controlled. Here we show, for the first time, how the structural …
Ferrous to Ferric Transition in Fe‐Phthalocyanine Driven by NO2 Exposure
Due to its unique magnetic properties offered by the open‐shell electronic structure of the
central metal ion, and for being an effective catalyst in a wide variety of reactions, iron …
central metal ion, and for being an effective catalyst in a wide variety of reactions, iron …
Cobalt atoms drive the anchoring of Co-TPP molecules to the oxygen-passivated Fe (0 0 1) surface
We present a multitechnique investigation of the structural and electronic properties of the
prototypical system composed by ultra-thin films of magnetic molecules [Co-tetraphenyl …
prototypical system composed by ultra-thin films of magnetic molecules [Co-tetraphenyl …