Hydrosilylation of olefins is the key catalytic reaction for the production of industrially
important organosilicon compounds such as organofunctional silanes and silicones …

The metal‐catalysed hydrofunctionalisation of alkenes and alkynes provides a convenient
and atom‐economic route to diversely functionalised products with control of regio‐, chemo …

The field of multimetallic catalysis is rapidly developing and some multimetallic complexes
catalyze organic transformations to yield the desired products in more efficient ways owing …

This paper addresses a review of platinum-based hydrosilylation catalysts. The main field of
application of these catalysts is the curing of silicone polymers. Since the 1960s, this area …

The tertiary amide is a ubiquitous functional group and plays an irreplaceable role in
medicinal chemistry. Its robust nature has meant—in the past—that selective manipulation of …

A highly regio-, diastereo-, and enantioselective, scalable Ir-catalyzed hydroarylation of
electron-rich acyclic and tensioned cyclic olefins with heterobiaryls is described. The …

Many efficient stereo-and regio-selective methodologies for synthesis of substituted
vinylsilanes have been reported, involving mostly classical stoichiometric routes as well as …

The iridium-catalyzed carbonyl-directed hydroarylation of monosubstituted alkenes
developed by Bower and co-workers [Crisenza, GEM; McCreanor, NG; Bower, JFJ Am …

Density functional calculations have been carried out to understand the anti-addition
stereochemistry and Markovnikov regiochemistry of the hydrosilylation of terminal alkynes …

The first highly efficient ligand-controlled regio-and stereodivergent intermolecular
hydrosilylations of internal alkynes have been disclosed. Cationic ruthenium complexes …