Agostic interactions in transition metal compounds

M Brookhart, MLH Green… - Proceedings of the …, 2007 - National Acad Sciences
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Biochemical mechanisms of cisplatin cytotoxicity

V Cepeda, MA Fuertes, J Castilla… - Anti-Cancer Agents …, 2007 - ingentaconnect.com
Since the discovery by Rosenberg and collaborators of the antitumor activity of cisplatin 35
years ago, three platinum antitumor drugs (cisplatin, carboplatin and oxaliplatin) have …

Transition metal complexation of σ bonds

RH Crabtree - Angewandte Chemie International Edition in …, 1993 - Wiley Online Library
The first σ complexes were found in the 1960s and 1970s, but they did not attract more than
passing attention. Only now are we beginning to recognize their key role in the chemical …

The gold–hydrogen bond, Au–H, and the hydrogen bond to gold, Au⋯ H–X

H Schmidbaur, HG Raubenheimer… - Chemical Society …, 2014 - pubs.rsc.org
In the first part of this review, the characteristics of Au–H bonds in gold hydrides are
reviewed including the data of recently prepared stable organometallic complexes with gold …

Indirect Nonbonded Nuclear Spin–Spin Coupling: A Guide for the Recognition and Understanding of “Through-Space” NMR J Constants in Small Organic …

JC Hierso - Chemical reviews, 2014 - ACS Publications
Nuclear magnetic resonance (NMR) is widely employed for investigating a range of
important issues from the determination of novel molecular structures in inorganic, organic …

Interactions between C H and N H bonds and d8 square planar metal complexes: hydrogen bonded or agostic?

W Yao, O Eisenstein, RH Crabtree - Inorganica chimica acta, 1997 - Elsevier
The structural characteristics of C H… M and N H… M groups in square planar d8-ML4
metal complexes are examined and compared w those for C H… M groups in …

The chemistry of binuclear palladium (II) and platinum (II) complexes

VK Jain, L Jain - Coordination Chemistry Reviews, 2005 - Elsevier
The chemistry of binuclear palladium (II) and platinum (II) complexes has been reviewed.
This review deals with complexes derived from various classes of ligands and covers …

Hydrogen bonds to Au atoms in coordinated gold clusters

MA Bakar, M Sugiuchi, M Iwasaki, Y Shichibu… - Nature …, 2017 - nature.com
It is well known that various transition elements can form M··· H hydrogen bonds. However,
for gold, there has been limited decisive experimental evidence of such attractive …

Cadmium (II) and Nickel (II) complexes of benziporphyrins. A study of weak intramolecular metal− arene interactions

M Stȩpień, L Latos-Grażyński… - Journal of the …, 2004 - ACS Publications
Weak metal− arene interactions have been investigated in Zn, Cd, Hg, and Ni complexes of
meso-tetraaryl m-and p-benziporphyrin (1 and 2) and of the new compound, m …

Transcyclometalation Processes with Late Transition Metals:  Caryl−H Bond Activation via Noncovalent C−H···Interactions

M Albrecht, P Dani, M Lutz, AL Spek… - Journal of the …, 2000 - ACS Publications
The bis (ortho-) chelated platinum complex [PtCl (NCN)], 1 (NCN=[C6H3 (CH2NMe2) 2-2, 6]-
), has been used as a novel metal precursor for C− H bond activation and subsequent …