First glycine isomer detected in the interstellar medium: glycolamide (NH2C (O) CH2OH)

VM Rivilla, M Sanz-Novo, I Jiménez-Serra… - The Astrophysical …, 2023 - iopscience.iop.org
We report the first detection in the interstellar medium (ISM) of a C 2 H 5 O 2 N isomer: syn-
glycolamide (NH 2 C (O) CH 2 OH). The exquisite sensitivity at sub-mK levels of an …

Quantum Chemistry and Astrochemistry: A Match Made in the Heavens

RC Fortenberry - The Journal of Physical Chemistry A, 2024 - ACS Publications
Quantum chemistry can uniquely answer astrochemical questions that no other technique
can provide. Computations can be parallelized, automated, and left to run continuously …

JWST Observations of Young protoStars (JOYS+): Detecting icy complex organic molecules and ions-I. CH4, SO2, HCOO−, OCN−, H2CO, HCOOH, CH3CH2OH …

WRM Rocha, EF van Dishoeck, ME Ressler… - Astronomy & …, 2024 - aanda.org
Context. Complex organic molecules (COMs) are ubiquitously detected in the gas phase
and thought to be mostly formed on icy grains. Nevertheless, there have not been any …

Discovery of the elusive carbonic acid (HOCOOH) in space

M Sanz-Novo, VM Rivilla, I Jiménez-Serra… - The Astrophysical …, 2023 - iopscience.iop.org
A quarter century after the detection of the last interstellar carboxylic acid, acetic acid (CH 3
COOH), we report the discovery of a new one, the cis-trans form of carbonic acid …

Amides inventory towards the G+ 0.693− 0.027 molecular cloud

S Zeng, VM Rivilla, I Jiménez-Serra… - Monthly Notices of …, 2023 - academic.oup.com
Interstellar amides have attracted significant attentions as they are potential precursors for a
wide variety of organics essential to life. However, our current understanding of their …

Molecular precursors of the RNA-world in space: New nitriles in the G+ 0.693− 0.027 molecular cloud

VM Rivilla, I Jiménez-Serra, J Martín-Pintado… - Frontiers in Astronomy …, 2022 - frontiersin.org
Nitriles play a key role as molecular precursors in prebiotic experiments based on the RNA-
world scenario for the origin of life. These chemical compounds could have been partially …

Conformer-specific desorption in propanol ices probed by chirped-pulse millimeter-wave rotational spectroscopy

Q Borengasser, T Hager… - The Journal of …, 2023 - ACS Publications
We present a new technique for the detection of molecules desorbed from an ice surface
using broad-band millimeter-wave rotational spectroscopy. The approach permits …

Laboratory spectroscopy of allylimine and tentative detection towards the G+ 0.693-0.027 molecular cloud

D Alberton, L Bizzocchi, N Jiang, M Melosso… - Astronomy & …, 2023 - aanda.org
Context. Substituted methanimines and ethylenes have been identified in the interstellar
medium. Therefore, allylimine (CH 2= CH–CH= NH) represents a promising candidate for a …

Millimetre and submillimetre spectroscopy of isobutene and its detection in the molecular cloud G+ 0.693

M Fatima, HSP Müller, O Zingsheim, F Lewen… - Astronomy & …, 2023 - aanda.org
Context. Isobutene ((CH 3) 2 C= CH 2) is one of the four isomers of butene (C 4 H 8). Given
the detection of propene (CH 3 CH= CH 2) toward TMC-1, and also in the warmer …

The first detection of SiC2 in the interstellar medium

S Massalkhi, I Jiménez-Serra, J Martín-Pintado… - Astronomy & …, 2023 - aanda.org
We report the first detection of SiC 2 in the interstellar medium. The molecule was identified
through six rotational transitions toward G+ 0.693-0.027, a molecular cloud located in the …