One of the attractive properties of the hollow carbon clusters, known as fullerenes, is the
possibility to use them as robust containers for other species. Although an IUPAC …

Endohedral metallofullerenes (EMFs), a new class of hybrid molecules formed by
encapsulation of metallic species inside fullerene cages, exhibit unique properties that differ …

Organic electrochemistry is concerned with the reduction and oxidation of organic molecules
at electrodes. Although it is now more than 200 years ago that the so-called Volta pile was …

In this tutorial review taking X-ray crystallographically characterized compounds as a starting
point a walk is taken through the electronic and structural properties of endohedral …

Metal–metal bonding is crucial in chemistry for advancing our understanding of the
fundamental aspects of chemical bonds. Metal–metal bonds based on alkaline-earth (Ae) …

The nature of actinide–actinide bonds has attracted considerable attention for a long time,
especially since recent theoretical studies suggest that triple and up to quintuple bonds …

The row of endohedral fullerenes is extended by a new type of sulfur-containing
clusterfullerenes: the metal sulfide (M2S) has been stabilized within a fullerene cage for the …

The electrocatalytic properties of some endohedral fullerenes for hydrogen evolution
reactions (HER) were recently predicted by DFT calculations. Nonetheless, the experimental …

The last two decades have witnessed major advances in the synthesis and characterization
of endohedral fullerenes. These species have interesting physicochemical properties with …

Charge transfer is a general phenomenon observed for all endohedral mono-
metallofullerenes. Since the detection of the first endohedral metallofullerene (EMF), La …