Metal–organic frameworks and derived materials as photocatalysts for water splitting and carbon dioxide reduction

J Chen, R Abazari, KA Adegoke, NW Maxakato… - Coordination Chemistry …, 2022 - Elsevier
One of the currently proposed solutions for finding alternatives to fossil fuels and combating
environmental pollution concerns the development of advanced materials for clean and …

Trace to the source: self‐tuning of MOF photocatalysts

Z Qian, R Zhang, Y Xiao, H Huang… - Advanced Energy …, 2023 - Wiley Online Library
Benefitting from ultra‐high porosity, large specific surface area (SSA), and rich active sites,
metal–organic frameworks (MOFs) have emerged as a star material in energy and …

Merging molecular catalysts and metal–organic frameworks for photocatalytic fuel production

PM Stanley, J Haimerl, NB Shustova, RA Fischer… - Nature Chemistry, 2022 - nature.com
In the effort to generate sustainable clean energy from abundant resources such as water
and carbon dioxide, solar fuel production—the combination of solar-light harvesting and the …

Enhanced photocatalytic CO2 reduction by integrating an iron based metal-organic framework and a photosensitizer

N Liu, K Tang, D Wang, F Fei, H Cui, F Li, J Lei… - Separation and …, 2024 - Elsevier
The conversion of CO 2 into fuels via photoreduction is a promising method to reduce
environmental pollution and alleviate the energy crisis. Herein, we report iron-based metal …

Molecular Catalysis of Energy Relevance in Metal–Organic Frameworks: From Higher Coordination Sphere to System Effects

NF Suremann, BD McCarthy, W Gschwind… - Chemical …, 2023 - ACS Publications
The modularity and synthetic flexibility of metal–organic frameworks (MOFs) have provoked
analogies with enzymes, and even the term MOFzymes has been coined. In this review, we …

Switching excited state distribution of metal–organic framework for dramatically boosting photocatalysis

S Guo, LH Kong, P Wang, S Yao, TB Lu… - Angewandte …, 2022 - Wiley Online Library
Photosensitization associated with electron/energy transfer represents the central science of
natural photosynthesis. Herein, we proposed a protocol to dramatically improve the …

[HTML][HTML] Metal organic framework composites for reduction of CO2

KG Liu, F Bigdeli, A Panjehpour, A Larimi… - Coordination Chemistry …, 2023 - Elsevier
Global warming due to greenhouse gases is a major current environmental threat. In today's
world those applicable technologies which convert CO 2 into valuable and environmentally …

Rhodium-Based Metal–Organic Polyhedra Assemblies for Selective CO2 Photoreduction

AC Ghosh, A Legrand, R Rajapaksha… - Journal of the …, 2022 - ACS Publications
Heterogenization of molecular catalysts via their immobilization within extended structures
often results in a lowering of their catalytic properties due to a change in their coordination …

Nanoreactors for photocatalysis

C Wu, Z Xing, S Yang, Z Li, W Zhou - Coordination Chemistry Reviews, 2023 - Elsevier
Photocatalysis is a fundamental and promising strategy for solar energy conversion.
Photocatalytic reactions are divided into three basic steps: light absorption, photogenerated …

Nanosheet-Engineered NH2-MIL-125 with Highly Active Facets for Enhanced Solar CO2 Reduction

F Guo, M Yang, RX Li, ZZ He, Y Wang, WY Sun - ACS Catalysis, 2022 - ACS Publications
Rational engineering of metal–organic frameworks (MOFs) with maximum exposed highly
active facets for photocatalytic CO2 reduction is desirable yet remains greatly challenging …