Advances in design and biomedical application of hierarchical polymer brushes

R Yang, X Wang, S Yan, A Dong, S Luan… - Progress in Polymer …, 2021 - Elsevier
Recent decades have witnessed abundant research on surface modifications to hierarchical
polymer brushes for multiple biomedical applications. The rational design and spatial …

Less is more: A review of μL-scale of SI-ATRP in polymer brushes synthesis

K Ślusarczyk, M Flejszar, P Chmielarz - Polymer, 2021 - Elsevier
Current trends of sustainable chemistry drive the (re) search to implement economical yet
ecological synthetic solutions as surface-initiated atom transfer radical polymerization (SI …

Oxygen tolerance during surface-initiated photo-ATRP: Tips and tricks for making brushes under environmental conditions

G Gazzola, I Filipucci, A Rossa… - ACS Macro …, 2023 - ACS Publications
Achieving tolerance toward oxygen during surface-initiated reversible deactivation radical
polymerization (SI-RDRP) holds the potential to translate the fabrication of polymer brush …

Oxygen tolerant and cytocompatible Iron (0)-mediated ATRP enables the controlled growth of polymer brushes from mammalian cell cultures

A Layadi, B Kessel, W Yan, M Romio… - Journal of the …, 2020 - ACS Publications
The use of zerovalent iron (Fe0)-coated plates, which act both as a source of catalyst and as
a reducing agent during surface-initiated atom transfer radical polymerization (SI-ATRP) …

Surface-initiated photoinduced ATRP: Mechanism, oxygen tolerance, and temporal control during the synthesis of polymer brushes

W Yan, S Dadashi-Silab, K Matyjaszewski… - …, 2020 - ACS Publications
Surface-initiated, photoinduced atom transfer radical polymerization (SI-photoATRP)
enables the controlled and rapid synthesis of compositionally diverse polymer brushes over …

Translating Surface-Initiated Atom Transfer Radical Polymerization into Technology: The Mechanism of Cu0-Mediated SI-ATRP under Environmental Conditions

W Yan, M Fantin, ND Spencer, K Matyjaszewski… - ACS Macro …, 2019 - ACS Publications
The exceptional features of Cu0-mediated surface-initiated atom transfer radical
polymerization (Cu0 SI-ATRP), and its potential for implementation in technologically …

Surface-initiated cu (0)-mediated crp for the rapid and controlled synthesis of quasi-3d structured polymer brushes

T Zhang, EM Benetti, R Jordan - 2019 - ACS Publications
Surface-initiated controlled radical polymerization mediated by Cu (0) plate (SI-Cu (0) plate-
CRP) is an extremely effective and versatile technique for the synthesis of functional polymer …

Working electrode geometry effect: A new concept for fabrication of patterned polymer brushes via SI-seATRP at ambient conditions

M Flejszar, K Ślusarczyk, P Chmielarz, K Wolski… - Polymer, 2022 - Elsevier
First reports concerning the use of atom transfer radical polymerization (ATRP) to prepare
patterned hybrid materials appeared more than 20 years ago. However, the development of …

Influence of nanoconfinement on the pka of polyelectrolyte functionalized silica mesopores

R Brilmayer, S Kübelbeck, A Khalil… - Advanced Materials …, 2020 - Wiley Online Library
Functionalized ordered mesoporous materials are relevant in technologies, such as drug
release, sensing, and separation. To design functionality, the silica framework can be …

Toward ultimate control of radical polymerization: functionalized metal–organic frameworks as a robust environment for metal-catalyzed polymerizations

HC Lee, J Hwang, U Schilde, M Antonietti… - Chemistry of …, 2018 - ACS Publications
Herein, an approach via combination of confined porous textures and reversible
deactivation radical polymerization techniques is proposed to advance synthetic polymer …