Stimuli responsive dynamic transformations in supramolecular gels
Supramolecular gels are formed by the self-assembly of small molecules under the
influence of various non-covalent interactions. As the interactions are individually weak and …
influence of various non-covalent interactions. As the interactions are individually weak and …
A Unique Temperature‐Induced Reverse Supramolecular Chirality‐Assisted Gel‐to‐Gel Transition
DK Duraisamy, SMM Reddy, P Saveri… - Macromolecular …, 2024 - Wiley Online Library
Supramolecular hydrogels typically undergo a gel‐to‐sol transition with heat, as
intermolecular interactions within the gel weaken. Although gel‐to‐gel transitions during …
intermolecular interactions within the gel weaken. Although gel‐to‐gel transitions during …
Photoinduced [2+ 2] and [4+ 4] Cycloaddition and Cycloreversion Reactions for the Development of Photocontrollable DNA Binders
C Dohmen, H Ihmels - ChemPhotoChem, 2024 - Wiley Online Library
In the current field of photopharmacology, molecular photoswitches are applied whose
interactions with DNA can be triggered or controlled by light. And although several …
interactions with DNA can be triggered or controlled by light. And although several …
Photochemical [2+ 2] polymerization of metal–organic gels of a rigid and angular diene with silver-salts of diverse anions: selective dye-sorption and luminescence by …
Two similar types of dienes, one rigid and the other flexible, were explored for their gel
formation abilities with Ag (I) salts. The rigid and angular dienes have shown an exceptional …
formation abilities with Ag (I) salts. The rigid and angular dienes have shown an exceptional …
Solid or gel? Which one works better for [2+ 2] photochemical polymerization in pyridine appended flexible phenylene 1, 4-bis-olefins by Ag (i) templation?
Two diene molecules were shown to undergo photopolymerization reactions in their metal–
organic gels and xerogels, while their respective crystalline CPs are photostable. These …
organic gels and xerogels, while their respective crystalline CPs are photostable. These …
The effect of vicinal di-halo substituents on the organogelling properties of aromatic supramolecular gelators and their application as soft templates
AS Mac Cormack, VM Busch, ML Japas… - New Journal of …, 2020 - pubs.rsc.org
A pronounced effect of vicinal dihalogen substituents on the gelling properties of aromatic
low molecular weight organogelators is reported. A new family of N, N′-(4, 5-dihalogen-1, 2 …
low molecular weight organogelators is reported. A new family of N, N′-(4, 5-dihalogen-1, 2 …
Organic Polymers of an Angular Diene via Solid State [2+ 2] Polymerization: Coordination Polymers with Dicarboxylates as Templates
A new class of organic polymers have been synthesized via solid-state [2+ 2]
photopolymerization reaction of coordination polymers (CPs) of an angular diene, namely, 3 …
photopolymerization reaction of coordination polymers (CPs) of an angular diene, namely, 3 …
Molecular environment and reactivity in gels and colloidal solutions under identical conditions
P Groves, J Huang, A Heise, J Marsh… - Physical chemistry …, 2020 - pubs.rsc.org
A PEG–Tyr block copolymer forms a kinetically stable colloidal solution in water at room
temperature which undergoes an irreversible conversion to a gel phase upon heating. A …
temperature which undergoes an irreversible conversion to a gel phase upon heating. A …