Transition metals-catalyzed amination of biomass feedstocks for sustainable construction of N-heterocycles

Q Yan, X Wu, H Jiang, H Wang, F Xu, H Li… - Coordination Chemistry …, 2024 - Elsevier
Transition metals, which are of diversity in their bonding orbitals, have a variety of significant
oxidation states and more complex chemical properties compared to the main group metals …

Hydroxymethylfurfural, a versatile platform chemical made from renewable resources

RJ van Putten, JC Van Der Waal, ED De Jong… - Chemical …, 2013 - ACS Publications
Over the last century, the world has become increasingly dependent on oil as its main
source of chemicals and energy. Driven largely by the strong economic growth of India and …

Recent advances in catalytic transformation of biomass-derived 5-hydroxymethylfurfural into the innovative fuels and chemicals

L Hu, L Lin, Z Wu, S Zhou, S Liu - Renewable and Sustainable Energy …, 2017 - Elsevier
In contrast to the nonrenewable fossil resources, biomass, the only renewable resource of
organic carbon in the nature, is considered as a special kind of inexhaustible feedstocks …

5-Hydroxymethylfurfural (HMF) as a building block platform: Biological properties, synthesis and synthetic applications

AA Rosatella, SP Simeonov, RFM Frade… - Green chemistry, 2011 - pubs.rsc.org
The biorefinery is an important approach for the current needs of energy and chemical
building blocks for a diverse range of applications, that gradually may replace current …

Catalytic advances in the production and application of biomass-derived 2, 5-dihydroxymethylfuran

L Hu, J Xu, S Zhou, A He, X Tang, L Lin, J Xu… - ACS …, 2018 - ACS Publications
In recent years, 2, 5-dihydroxymethylfuran (DHMF), which can be produced by the selective
hydrogenation of biomass-derived 5-hydroxymethylfurfural (HMF), has attracted great …

Chemical routes for the transformation of biomass into chemicals

A Corma, S Iborra, A Velty - Chemical reviews, 2007 - ACS Publications
Vegetable biomass is generated from CO2 and H2O using sunlight as the energy source,
producing O2 as a subproduct. The primary products formed are C6-and C5-sugars that …

Electrochemistry for biofuel generation: production of furans by electrocatalytic hydrogenation of furfurals

P Nilges, U Schröder - Energy & Environmental Science, 2013 - pubs.rsc.org
The electrochemical conversion of furfural to 2-methylfuran (MF) and of 5-
hydroxymethylfurfural (5-HMF) to 2, 5-dimethylfuran (DMF) by means of a room-temperature …

Cycloamination strategies for renewable N-heterocycles

H Li, H Guo, Z Fang, TM Aida, RL Smith - Green Chemistry, 2020 - pubs.rsc.org
Biomass resources have infinite possibilities for introducing nitrogen, sulfur, or phosphorus
heteroatoms into their structures by virtue of controllable carbon–heteroatom bond …

Use of Lawesson's reagent in organic syntheses

T Ozturk, E Ertas, O Mert - Chemical reviews, 2007 - ACS Publications
Transformation of a carbonyl functional group into thiocarbonyl has been an important
interest to synthetic organic chemists for many years. Two reagents, phosphorus …

Unsaturated O- and N-Heterocycles from Carbohydrate Feedstocks

FW Lichtenthaler - Accounts of chemical research, 2002 - ACS Publications
With reference to the impending transition of chemical industry from depleting fossil raw
materials to renewable feedstocks the end of cheap oil is predicted for 2040 at the latest this …