Carbenes and nitrenes can exist in both singlet and triplet states, sometimes equally stable
and interconverting either thermally or photochemically. Many carbene and nitrene reactions …

Flash vacuum pyrolysis (FVP) of azides is an extremely valuable method of generating
nitrenes and studying their thermal rearrangements. The nitrenes can in many cases be …

The exceptional reactivity of the azide group makes organic azides a highly versatile family
of compounds in chemistry and the material sciences. One of the most prominent reactions …

Mechanochemical reactions studied by in situ Raman spectroscopy: base catalysis in liquid-assisted
grinding - Chemical Communications (RSC Publishing) DOI:10.1039/C5CC01915J Royal …

The discovery of functional RNAs that are critical for normal and disease physiology
continues to expand at a breakneck pace. Many RNA functions are controlled by the …

The potential‐energy surfaces of the reactions of dirhodium tetracarboxylate (Rh2II, II)
catalyzed nitrene (NR) insertion into C H bonds were examined by a DFT computational …

Density functional theory (DFT), CCSD (T), and CBS-QB3 calculations were performed to
understand the chemical and reactivity differences between acetylnitrene (CH3C (O) N) and …

A density functional theory (DFT) study has been conducted to elucidate the mechanism of
the rhodium (III)-catalyzed C–H activation of N-phenoxyacetamide, where the amido …

The mutual interconversion and decomposition reactions of four tetrazole isomers (1H-TZ,
2H-TZ, 5H-TZ, and an N-heterocyclic carbene 14H) have been studied theoretically using …

Visible light sensitization of benzoyl azides was examined in reaction with N-
phenylmethacrylamides to afford biologically important oxindoles and spirooxindoles via a …